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The cycloaddition of carbon dioxide into value-added chemicals is of great significance to reduce the carbon-emission. Herein, a Mn-based coordination polymer [(CH3)2NH2]2n[Mn3(L)2]n·nDMF·0.5nH2O (JLNU-104) has been constructed by the solvothermal reaction...

To investigate the facile synthesis strategy for MOF-based plasomic photocatalyst, an Ag(I)-organic framework [Ag3(psa)(4,4’-bpy)3]·OH·2CH3OH·2H2O (JLNU-91) was prepared by employing phenylsuccinic acid (H2psa) and 4,4’-bipyridine (4,4’-bpy) under room temperature. With irradiation...

A novel anionic Cd-MOF ([(CH3)2NH2]n[Cd(HL)DMF]n·2nH2O·nDMF, H4L = 1,2,4,5-tetrakis[(4-carboxy)phenoxymethyl]benzene) was synthesized for the first time. It, as precursor, was utilized to achieve Fe@Cd-MOF crystals via the substitution of Fe3+ ions due...

Owing to the uniformly separated metal sites and regular structures, Ag(I)-based coordination polymers (CPs) have been considered as promising platforms for plasmonic photocatalysts. Herein, a novel Ag(I)-CP [Ag2(NO2-bdc)(4,4’-bpy)2]·2CH3CN·2.5H2O (JLNU-90, NO2-bdc...