Human urine is universal unused waste material that is regularly disposed of by the human body. We, for the first time, presented an economically beneficial, sustainable, and novel route to synthesize mesoporous human urine carbon (HUC)-containing heteroatoms, i.e., C, Na, Cl, N, S, and P, using a human urine waste. The as-synthesized HUC were envisaged for their structural elucidation, morphology evolution, crystal structure, functional bonding, and elemental composition analyses through various sophisticated technologies. The HUC catalyst had a moderately crystalline nature due to the graphitic phase of carbon with a particle size of 20–50 nm, which was successfully used to synthesizing chromenes, 1,8-di-oxo-octahydroxanthenes, and benzypyrazolylcoumarin and biscoumarin derivatives through a one-pot multicomponent reaction with 20 mg of catalyst in EtOH/H2O solvent. This eco-friendly and simple method offers numerous advantages such as easy purification, clean reaction, and excellent yield for organic synthesis. The HUC catalyst can be recycled ten times and reused multiple times after activation without affecting catalytic performance.
Various b-aminoketones were synthesized in a three-component reaction of ketones, aldehydes, and amines in the presence of calcium chloride as catalyst in ethanol in high yields as compared to other synthetic methods. The advantages of this new method are a short reaction time (2 h), high yields, easy workup, convenience, low cost, and eco-friendly protocol.
A simple and environmentally benign procedure for the bromination of substituted α,β-unsaturated ketones in good yield has been described using ammonium bromide as a brominating agent and ceric ammonium nitrate (CAN) as a single-electron oxidant to afford α,β-dibromoketones. The reaction involves C-Br bond formation by radical method generated by CAN. The reaction can be carried out by either at room temperature, stirring in solvent CH
Tungsten oxide (WO3) as an efficient heterogeneous catalyst was prepared via a simple hydrothermal route for the synthesis of a wide range of bioactive heterocyclic compounds.
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