Aim:
The objective of the review paper aims to explore and to provide the insight of various low-cost adsorbents prepared and used in the removal of hazardous dye pollutants from the contaminated industrial effluents.
Background:
The major untreated discharge from the textile industries constitutes a wide range of organic contaminants with the enhanced concentration of biological oxygen demand and chemical oxygen demand inthe water bodies. Dyes are considered as the major water contaminants and this quest the researchers to adopt various technologies to remove the hazardous dye pollutants from the aquatic environment. Dyes are the chemical compounds that tend to adhere themselves with metal or salts by covalent bond formation or complexes by mechanical retention or physical adsorption so as to impart colours to which it is being applied.
Objective:
Numerous treatment methodologies which have been applied to the degradation of dyes. The current study has been focused on the distinct low cost and cost-effective adsorbents used in the removal of various dye pollutants. Also, the application of nanoparticles in the removal of the hazardous dye pollutants had received great interest because of its size and high reactive nature.
Methods:
The treatment technologies used in the removal of dye pollutants from wastewater have been listed as adsorption, coagulation, electrocoagulation, flocculation, membrane filtration, oxidation and biological treatment.
Results:
The complex structure of the dyes causes a great harmful impact on the aquatic environment. Though numerous treatment technologies have been applied, adsorption has been preferred by various researchers because of its cost-effective nature.
Conclusion:
The various adsorbents are used in the removal of cationic, anionic and non-ionic dyes. The different types of adsorbent from agricultural waste, activated carbons, nanomaterials and biomaterials have been discussed with the advantages and limitations.
In the present study, the synthesis of CoWO4 (CWO)–Ni nanocomposites was conducted using a wet chemical method. The crystalline phases and morphologies of the Ni nanoparticles, CWO, and CWO–Ni composites were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDAX). The electrochemical properties of CWO and CWO–Ni composite electrode materials were assessed by cyclic voltammetry (CV), and galvanostatic charge–discharge (GCD) tests using KOH as a supporting electrolyte. Among the CWO–Ni composites containing different amounts of Ni1, Ni2, and Ni3, CWO–Ni3 exhibited the highest specific capacitance of 271 F g−1 at 1 A g−1, which was greater than that of bare CWO (128 F g−1). Moreover, the CWO–Ni3 composite electrode material displayed excellent reversible cyclic stability and maintained 86.4% of its initial capacitance after 1500 discharge cycles. The results obtained herein demonstrate that the prepared CWO–Ni3 nanocomposite is a promising electrode candidate for supercapacitor applications.
Treatment and safe disposal of tannery saline wastewater, a primary effluent stream that is generated by soaking salt-laden hides and skin is one of the major problems faced by the leather manufacturing industries.Conventional treatment methods like solar evaporation ponds and land composting are not eco-friendly as they deteriorate the ground water quality. Though, this waste stream is comprised of high concentration of dissolved proteins the presence of high salinity (1-6 % NaCl by wt) makes it non-biodegradable. Enzymatic treatment is one of the positive alternatives for management of such kind of waste streams. A novel salttolerant alkaline protease obtained from P.aeruginosa (isolated from tannery saline wastewater) was used for enzymatic degradation studies. The effect of various physical factors including pH, temperature, incubation time, protein source and salinity on the activity of identified protease were investigated. Kinetic parameters (K m , V max ) were calculated for the identified alkaline protease at varying substrate concentrations. Tannery saline wastewater treated with identified salt tolerant protease showed 75 % protein removal at 6 h duration and 2 % (v/v) protease addition was found to be the optimum dosage value.
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