AbstrakSistem adsorpsi adalah salah satu cara atau metoda yang paling efektif untuk memisahkan CO 2 dengan zat lainnya yang dihasilkan dari pembakaran bahan bakar fosil. Pada rancangan untuk aplikasi tersebut, disamping data karakteristik material berpori (adsorben), data penyerapan CO 2 pada adsorben (kinetik dan thermodinamika) juga dibutuhkan. Penelitian ini bertujuan menghasilkan data adsorpsi isotermal pada tekanan sampai dengan 3,5 MPa dengan menggunakan metoda tak langsung (metoda volumetrik) pada temperatur isotermal 300, 308, 318 dan 338 K. Adsorben yang digunakan adalah karbon aktif berbahan dasar batubara Kalimantan Timur yang diproduksi dengan menggunakan metode aktivasi fisika (CO 2 ) derngan luas permukaan karbon aktif (karbon aktif KT) adalah 668 m 2 /g dan volume porinya 0,47 mL/g. Karbon dioksida (CO 2 ) yang digunakan adalah karbon dioksida high purity dengan kemurnian 99,9%. Data yang diperoleh dari hasil eksperimen kemudian dikorelasi dengan menggunakan model persamaan Langmuir dan Toth. Hasil penelitian menunjukkan bahwa Kapasitas penyerapan maksimum adalah 0,314 kg/kg pada temperatur 300 K dan tekanan equilibrium 3384,69 kPa. Hasil regresi data eksperimen dengan menggunakan model Langmuir dan Toth adalah 3,4% dan 1,7%. AbstractHigh Pressure Adsorption Isotherm of CO 2 on Activated Carbon using Volumetric Method. Adsorption system is ones of the most effective methods for CO 2 separating with other substances that produced from the burning of fossil fuels. In the design for that application, beside of characteristics of porous material (adsorbent) data, CO 2 adsorption data on the adsorbent (kinetic and thermodynamic) are also needed. The aim of this research is resulting isothermal adsorption data at pressures up to 3.5 MPa by indirect methods (volumetric method) at isothermal temperature of 300, 308, 318 and 338 K. Adsorbent that used in this research is activated carbon made from East of Kalimantan coals by physical activation method (CO 2 ) which is the surface area of activated carbon is 668 m 2 /g and pore volume is 0.47 mL/g. Carbon dioxide (CO 2 ) that used in this research is high purity carbon dioxide with a purity of 99.9%. Data from the experiment results then correlated using the Langmuir and Toth equations model. The results showed that the maximum adsorption capacity is 0.314 kg/kg at 300 K and 3384.69 kPa. The results of regression of experiment data using Langmuir and Toth models were 3.4% and 1.7%.
Air pollution in major cities in many countries has reaching a very concerning level. One of thecause of air pollution is pollution caused by smoke aerosol. Smoke aerosols that has an averageparticle diameter of 0.1 μm – 1 μm can be found in cigarette smoke, diesel vehicle fume, industrialfume and many else. This condition will be worsen by the increase in the number of smokers, motorvehicles and industry. Therefore we need to pursue the control method for that kind of air pollution.In the literature study, it’s found that the cleaning method of air fi ltration for fi ne particle withdimension of 0.01 – 5 μm are by using thermal precipitator. Thermal precipitator is one method ofair fi ltration based on thermophoretic force, which is if there is a temperature difference betweentwo plates, it will cause the force that will push the particles between the two plates toward theplate that has lower temperature. In the effort to help control and reduce the air pollution, for thisstudy we made a thermal precipitator test equipment to deposit the particles in the air with the useof thermophoretic force. That force is the force applied to the particles that suspended in the fl uidfl ow. The temperature difference between two plates is set at ΔT=5, 10, 15, and 20oC. This studyutilized gas sensors to observe the characterization of thermal precipitator. From the experimentand analysis can be concluded that thermal precipitator can be applied as a smoke collector.
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