MIL-101(Cr) and water were applied to adsorption refrigeration technology. MIL-101(Cr) was prepared by hydrothermal synthesis method and characterized by X-ray diffraction patterns (XRD), Fourier transform infrared spectroscopy (FTIR), N2 adsorption–desorption measurement at 77 K, thermal gravimetric analysis (TGA) and scanning electron microscope (SEM). The adsorption isotherms of water vapor on MIL-101(Cr) were investigated by using a gravimetric water sorption analyzer. This study established the basic adsorption cycle mathematical model and used MATLAB/Simulink for the simulation. The control variable method was used to simulate the effect on the cooling capacity and coefficient of performance (COP) when the desorption temperature changed. When the adsorption temperature was 35 °C, the evaporation temperatures were 15 °C and 20 °C, and the amount of water vapor equilibrium adsorption on MIL-101 (Cr), Cooling power per unit adsorbent mass (SCP), and COP were measured by using the adsorption performance test rig on the basis of a new type of powder adsorbent filling method.
An MIL-101(Cr) powder material was successfully prepared using the hydrothermal synthesis method, and then the original MIL-101(Cr) was combined with different mass fractions of CaCl2 using the immersion method to obtain a MIL-101(Cr)/CaCl2 composite material. The physical properties of the adsorbent were determined by X-ray powder diffraction (XRD), an N2 adsorption desorption isotherm test, and thermogravimetric analysis (TG). The water vapor adsorption performance of the metal-organic frameworks MOFs was tested with a gravimetric water vapor adsorption instrument to analyze its water vapor adsorption mechanism. Based on the SIMULINK platform in the MATLAB software, a simulation model of the coefficient of performance (COP) and cooling capacity of the adsorption refrigeration system was established, and the variation trends of the COP and cooling capacity of the adsorption refrigeration system under different evaporation/condensation/adsorption/desorption temperatures was theoretically studied. MIL101-(Cr)/CaCl2-20% was selected as the adsorption material in the adsorption refrigeration system through the physical characterization of composite materials with different CaCl2 concentrations by means of adsorption water vapor test experiments. A closed adsorption system performance test device was built based on the liquid level method. The cooling power per unit and adsorbent mass (COP and SCP) of the system were tested at different evaporation temperatures (288 K/293 K/298 K); the adsorption temperature was 298 K, the condensation temperature was 308 K, and the desorption temperature was 353 K. The experimental results showed that COP and SCP increased with the increase in the evaporation temperature. When the evaporation temperature was 298 K, the level of COP was 0.172, and the level of SCP was 136.9 W/kg. The COP and SCP of the system were tested at different adsorption temperatures (293 K/298 K/303 K); the evaporation temperature was 288 K, the condensation temperature was 308 K, and the desorption temperature was 353 K. The experimental results showed that the levels of COP and SCP decreased with the increase in the adsorption temperature. When the adsorption temperature was 293 K, the level of COP was 0.18, and the level of SCP was 142.4 W/kg.
Summary At present, all types of large–medium‐sized supermarkets with aquatic products adopt ice preservation to ensure freshness. The traditional method of ice preservation needs to make a large amount of thick ice and thus wastes manpower and freshwater. A new ice preservation system with cold storage (IP&CS) is designed, and its performance is tested. The use of a cold storage tank to replace the thick ice laid achieves a repeated cold storage and discharge. This experiment uses NaCl solution as the cold storage phase change material (PCM). The phase change temperature of the cold storage PCM and the optimum temperature of the secondary refrigerant during the cold storage process are determined. Results show that the center temperature of aquatic products, water loss rate, color of aquatic products, power consumption, and electricity cost of the IP&CS system are better than those of the traditional ice preservation system.
Nonlinear dynamic response with stability analysis of a sandwich structure with flexible core are investigated by integration of variational asymptotic method (VAM) and the first-order shear deformation theory. A simply supported sandwich structure is subjected to an harmonic transverse excitation in thermal environments. Generalized 2 D Reissner-Mindlin type stiffness matrices including an equivalent transverse shear matrix are obtained based on through-the-thickness analysis using VAM without invoking any ad hoc kinematic assumptions. The governing equation is derived using Hamilton’s principle taking into account von K[Formula: see text]rm[Formula: see text]n geometric nonlinearity. Galerkin’s method is employed to develop a nonlinear differential equation of the problem with quadratic and cubic nonlinearities, which are associated with the coupling of the in-plane stretching and transverse deflection due to thermal moments. Periodic solutions are determined using the incremental harmonic balance (IHB) method and incremental arc-length technique. The stability is evaluated by Routh-Hurwitz theory. The effects of the temperature variation, geometric parameters and material properties on the resonance as well as amplitude of steady state vibration are investigated through a detail parametric study.
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