Factor analysis utilizes the covariance
of compositional variables
to separate sources of ambient pollutants like particulate matter
(PM). However, meteorology causes concentration variations in addition
to emission rate changes. Conventional positive matrix factorization
(PMF) loses information from the data because of these dilution variations.
By incorporating the ventilation coefficient, dispersion normalized
PMF (DN-PMF) reduces the dilution effects. DN-PMF was applied to hourly
speciated particulate composition data from a field campaign that
included the start of the COVID-19 outbreak. DN-PMF sharpened the
morning coal combustion and rush hour traffic peaks and lowered the
daytime soil, aged sea salt, and waste incinerator contributions that
better reflect the actual emissions. These results identified significant
changes in source contributions after the COVID-19 outbreak in China.
During this pandemic, secondary inorganic aerosol became the predominant
PM2.5 source representing 50.5% of the mean mass. Fireworks
and residential burning (32.0%), primary coal combustion emissions
(13.3%), primary traffic emissions (2.1%), soil and aged sea salt
(1.2%), and incinerator (0.9%) represent the other contributors. Traffic
decreased dramatically (70%) compared to other sources. Soil and aged
sea salt also decreased by 68%, likely from decreased traffic.
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