The effusive six months long 2014-2015 Bárðarbunga eruption (31 August-27 February) was the largest in Iceland for more than 200 years, producing 1.6 ± 0.3 km 3 of lava. The total SO 2 emission was 11 ± 5 Mt, more than the amount emitted from Europe in 2011. The ground level concentration of SO 2 exceeded the 350 µg m −3 hourly average health limit over much of Iceland for days to weeks. Anomalously high SO 2 concentrations were also measured at several locations in Europe in September. The lowest pH of fresh snowmelt at the eruption site was 3.3, and 3.2 in precipitation 105 km away from the source. Elevated dissolved H 2 SO 4 , HCl, HF, and metal concentrations were measured in snow and precipitation. Environmental pressures from the eruption and impacts on populated areas were reduced by its remoteness, timing, and the weather. The anticipated primary environmental pressure is on the surface waters, soils, and vegetation of Iceland.
The 2014 Bárðarbunga rifting event in Iceland resulted in a 6‐month long eruption at Holuhraun. This eruption was characterized by high lava discharge rate and significant gas emission. The SO2 flux for the first 3 months was measured with satellite sensors and the petrologic method. High‐resolution time series of the satellite data give 1200 kg/s that concurs with 1050 kg/s obtained from melt inclusion minus degassed lava sulfur contents scaled to the mass of magma produced. A high‐purity gas sample, with elevated S/Cl due to limited chlorine degassing, reveals a similar degassing pattern of trace metals as observed at Kīlauea (Hawai'i) and Erta Ale (Ethiopia). This suggests a common degassing mechanism at mantle plume‐related volcanoes. The trace metal fluxes, calculated from trace element to sulfur ratios in the gas sample and scaled to the sulfur dioxide flux, are 1–2 orders of magnitude stronger at Holuhraun than Kīlauea and Erta Ale. In contrast, volcanoes at convergent margins (Etna and Stromboli, Italy) have 1–2 orders of magnitude higher trace element fluxes, most likely caused by abundant chlorine degassing. This emphasizes the importance of metal degassing as chlorine species. Short‐lived disequilibria between radon daughters, 210Pb‐210Bi‐210Po measured in the gas, suggest degassing of a continuously replenished magma batch beneath the eruption site. Earlier and deep degassing phase of carbon dioxide and polonium is inferred from low (210Po/210Pb) in the gas, consistent with magma transfer rate of 0.75 m/s.
.[1] Sulfur concentrations have been measured in 28 melt inclusions (MIs) in plagioclase, clinopyroxene, and olivine crystals extracted from tephra produced during the explosive eruption of Grímsvötn in May 2011. The results are compared to sulfur concentrations in the groundmass glass in order to estimate the mass of sulfur brought to surface during the eruption. Satellite measurements yield order of magnitude lower sulfur (~0.2 Tg) in the eruption plume than estimated from the difference between MI and the groundmass glass. This sulfur "deficit" is readily explained by sulfur adhering to tephra grains but principally by sulfide globules caused by basalt-sulfide melt exsolution before degassing. A mass balance calculation reveals that approximately~0.8 Tg of SO 2 is present as globules, representing~50% of the total sulfur budget. Most of the sulfide globules likely reside at depth due to their elevated density, for potential later remobilization by new magma or hydrothermal circulation.
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