The aim of this paper is to present a chemical composition and quantities of mining and processing waste landfills material developed during historical mining and smelting. After detailed inspection, it was found that approximately 2.6 gigatons of the waste had been deposited at 1650 sites, covering almost 65 km2. More than half of this material, 55%, is characterized as conventional mining waste, 37% belongs to the processing tailings, and 8% to metallurgical waste. Most of these tailing sites are unclaimed, presenting a source of contamination for nearby communities. According to the literature data collected and additional chemical analyses, in accordance with zero-waste philosophy, about 42 promising locations (c. 270 million tons) could be selected, where various advanced eco-innovative methods of recovery could possibly apply. The areas with the highest prospective recovery are Serbia and Kosovo. In accordance with the metal prices achieved in March 2022, it is estimated that the recovery of tailings could bring up to 18,100 million USD, which is much more compared to the prices of March 2020—10,600 million USD—when the commodity market was governed by the COVID-19 restrictions. In addition to the commercial value of the metals, the environmental aspect should not be forgotten after the application of reuse and recycling concepts.
The sources of Zn, Pb and Cd in alluvial and stream sediments have been studied in the area of historical Zn smelting tradition. 30 samples of stream sediments and samples from 4 alluvial sediment profiles were collected. Fractions 0.125–0.063 and < 0.063 mm were analysed by the means of ICP-MS prior 4-acid digestion. The highest levels of Zn, Cd and Pb were detected in the alluvial sediments in the closest vicinity to the abandoned slag and ore roasting residue waste dumps, reaching 96 and 4520 mg/kg, 522 and 26,800 mg/kg and 3.7 and 31 mg/kg for Pb, Zn and Cd in stream and alluvial sediments, respectively. The Voglajna River then transports contamination particles into the Savinja River, which afterwards flows into the Sava River. Consequently, the anomaly can even be detected in the Sava River, more than 30 km downstream. Higher levels of Pb, Zn and Cd have been found in fraction < 0.063 mm compared to 0.125–0.063 mm fraction. Impacts of historically contaminated soil erosion and in particular the wash-out of Zn-smelting waste from the improperly managed waste dump were recognised as the dominant sources of Zn, Cd and Pb in the stream and alluvial sediments.
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