Ten Early Bronze Age (BzA1, 2200-2000 BC) copper artefacts from the central Valais region from Switzerland were studied for their elemental composition and lead isotope ratios. In order to answer the archaeological question of a local copper supply, a database for copper minerals across the Valais (Switzerland) has been established. This database contains 69 data on lead isotope ratios as well as additional information on the minerals and geochemical associations for copper minerals from 38 locations in the Valais. Comparisons of the artefacts were also made with data pertaining to minerals from various deposits from Europe and Anatolia taken from the literature. The provenance of the materials is very diverse. Some of the data are compatible with the data from the copper mineral deposits of the Valais region. Moreover, three copper lunulae were identified as possibly Tuscan, which demonstrates contacts between Italy and the Valais region. This pattern also establishes a multiplicity of provenances for the metal and cultural influences in the Alpine environment of the Rhone Valley of Switzerland at the beginning of the Early Bronze Age.

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Five experimental bloomery iron ore smelts were carried out in a reconstruction of an early medieval furnace of the Boécourt type (Switzerland). A part of the bloom from the most successful experiment was forged to a billet. Starting materials and products were weighed, described and chemically characterized (ICP-MS, LA-ICP-MS and WD-XRF). The calculation of the yield and mass balance based on the chemical analyses from the ore (optimum) and from the ore, furnace lining, slag and ash (applied) allow the determination and quantification of the materials involved in the process. This permits the interpretation of the quality of the experiments. The chemical characterization of metal produced from hematite ore from the Gonzen Mountains in Switzerland gives archaeologists the possibility to compare the metal of iron artefacts to metal from this mine. Finally a good agreementbetween experiments and archaeological reality can be shown.

This paper discusses the results of a study of the exploitation history of the metallogenic region of the Wallis, Switzerland. Periods of exploitation in this mining district are determined by comparisons of the lead isotope fingerprint of the mines with those of dated artefacts presumed to have a local origin based on the style of craftsmanship. The approach is based on the study of silver mines in the Wallis area and illustrated by three examples of local craftsmanship: (1) silver jewellery from the Late Iron Age, (2) a reliquary shrine from the Early Middle Ages and (3) silver coins from the Late Middle Age.

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