A cloud point extraction (CPE) method was developed for the separation and preconcentration of trace amounts of lead is combined with flame atomic absorption spectrometry (FAAS) to determine trace amounts of lead in brine water. The method is depended on the formation of the hydrophobic complex between Pb(II) and (APDC) followed by its extraction into a Triton X-114 using surfactant. The parameters such as pH of sample, concentrations ofAPDC and Triton X-114, equilibrium temperature, and equilibrium time, which affect both complexation and extraction, are optimized. Under the selected optimum conditions, and use of matrix modifying agents enable us to develop the direct method for determination Pb in brine water. The accuracy of the method was % (96)while the detection limit was found to be (0.1122 ppm) for preconcentration of 1.0 ml sample,for the determination of Pb(II) is obtained.