Here, we report on an electrochemical impedance study of silica of organic origin as an active electrode material. The electrode material obtained from carbonized marine biomass containing nanoporous diatoms has been characterised by means of XRD, IR, SEM and EIS. Different kinds of crystallographic phases of silica as a result of thermal treatment have been found. The electrode is electrochemically stable during subsequent cyclic voltammetry measurements taken in the potential range from 0.005 up to 3.0 V vs. Li/Li + . The material has been found to exhibit high charge capacitance of 521 mAh g −1 being cycled at a rate C/20 with capacity retention of about 97%. Electrochemical impedance spectroscopy performed at an equilibrated potential E = 0.1 V in the temperature range 288-294 K discloses low charge transfer resistivity and low diffusional impedance.
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