A skin-like cellulose biomimetic hydrogel was prepared based on dynamic covalent chemistry, which realized the combination of ultra-stretchability, self-healing, adhesiveness, antibacterial and mechano-stimuli sensitivity within a single structure.

A facile, environmentally benign approach has been developed for the preparation of dynamic, multiresponsive, and self-healing hydrogels from inexpensive bamboo pulp, poly(vinyl alcohol) (PVA), and borax. The microfibrillated cellulose (MFC) reinforced PVA−borax hydrogels were produced through a onepot route in conjunction with ball milling and physical blending in tandem in aqueous medium. In this way, MFC particles could be efficiently generated and well-dispersed in a polymer matrix, and they have been verified by scanning electron microscopy. The rheology analysis indicated a close relationship between the mechanical strength and the MFC loading and ball milling time. Due to the dynamic equilibrium of the didiol−borax linkages and the reinforcement of MFC fibers, the hydrogels showed enhanced self-healing behavior and mechanical stiffness, which was also supported by rheology analyses. In addition, the hydrogels were found to be sensitive to the pH value. The hydrogels present a solvent or gel state with the change of pH value, and this sol−gel transfer can be repeated while maintaining the shape, further demonstrating the dynamic reversible behavior of the hydrogels.

Gold-catalyzed reactions, which have been widely explored over the past several years, are powerful tools in organic synthesis to access complex molecular frameworks, and some corresponding excellent reviews have been reported. However, little attention has been paid to summarize the reactions of strained small-ring-containing molecules catalyzed by gold. This critical review mainly puts its emphasis on the recent progress in the field of gold-catalyzed transformations of cyclopropyl-, cyclopropenyl-, epoxy- and aziridinyl-containing molecules. The rapid construction of interesting building blocks in organic synthesis from strained small rings catalyzed by gold has been summarized in this review (106 references).