Slurry transport has become a subject of interest in several industries, including oil and gas. The importance of slurry/solid transport in the oil and gas industry is evident in areas of cuttings transport, sand transport and, lately, hydrates. There is therefore a great need to develop instrumentation capable of characterizing fluids with high solid content. Presence of solids in fluids makes the rheological characterization of these systems difficult. This is because available rheometers are designed with a narrow gap and cannot prevent solids from settling. The main aim of this paper is to present a step-by-step procedure of converting torque and shaft speed into viscosity information by applying the Couette analogy, equivalent diameter and inverse line concepts. The use of traditional impeller geometries such as cone and plate may be challenging due to their narrow gap and inability to prevent settling. Therefore, the use of nonconventional impeller geometry is imperative when dealing with settling slurries and suspensions. The most challenging task using complex geometry impeller is data interpretation especially when dealing with complex rheology fluids. In this work, an autoclave is transformed into a mixer-type viscometer by modifying its mixing, cooling and data acquisition systems. Mathematical models relating the measured torque to shear stress and the measured shaft speed to shear rate were developed and expressed in terms of the equivalent diameter. The shear rate and shear stress constants were expressed in terms of equivalent diameter and measureable parameters such as impeller speed and torque. The mixer-type viscometer was calibrated using four Newtonian and four Power-Law fluids to determine the rheological constants (equivalent diameter, shear rate and shear stress constants). The concept of inverse line was used to identify the laminar flow regime. The calibrated instrument was used to characterize two Power-Law fluids. This procedure can be extended to any rheological model. Methods developed in this work can be used to characterize fluids with high solid content. This is particularly important when dealing with complex rheology slurries such as those encountered in food processing, oil and gas and pharmaceuticals.Keywords Rheology Á Settling and non-settling slurries Á Hydrate slurry List of symbolsImpeller diameter (m) k

When the ambient temperature is below freezing point, ice may form in the oil transportation pipelines, which can cause flow assurance issues, such as restricting flow path or even plugging the pipeline. Ice plugging was reported to delay the restart of the Poplar pipeline system gathering crude oil from Montana and North Dakota. [1] Ice may also pose threats to the Trans-Alyeska Pipeline System (TAPS). The declining throughput makes the oil get colder much faster. If oil temperature falls below the freezing point, ice forms and leads to flow assurance issues, such as coating critical valves, accumulating in the pipeline, and restricting flow. [2] This paper investigates the fundamentals of ice formation in the pipeline and its effect on the transportation system. A 2-inch diameter carbon steel flow loop was instrumented to measure pressure, temperature, and differential pressure. The experimental results show that ice formation can restrict flow at the low sport in front of the flow meter, the inserted thermocouples, and the perforated plate. Annular ice deposition was found at the pipe wall. The morphology of the deposition is rime ice, indicating the deposition is due to small ice crystals sticking to the pipe surface. It was found that the formation of annular deposition requires a negative temperature gradient. The effect of water cuts and fluid properties on plugging tendency is discussed. The mechanisms for ice deposition along the pipe and plugging at the pipe components are proposed.

The formation of gas hydrates in subsea oil and gas flowlines is a major concern since this can cause production interruptions, and environmental and safety problems. Under gas hydrate formation conditions, hydrates can create flow restrictions, that may then lead to plugging of the flowline. The risks associated with hydrate formation in subsea flowlines increases significantly as the reservoir matures and the amount of produced water increases. The oil and gas industry recognizes the need for the investigation, development and implementation of better hydrate management strategies covering the gaps in current practices. In helping to develop better hydrate management strategies, hydrate formation in partially dispersed multiphase flow conditions were previously investigated using a high pressure industrial-scale flowloop (Vijayamohan et al. 2016). In our recent tests using the same flowloop, the effect of hydrate volume percent on the pressure drop of the system was evaluated. The amount of hydrate formed in the system was limited by systematically controlling system temperature and gas available for hydrate formation. In recent flowloop tests, it was also hypothesized that hydrate deposition on the pipe surface can contribute significantly to a rapid increase in the pressure drop (Grasso 2015). As such, an investigation into hydrate deposition mechanisms and their detection was performed. Deposition mechanisms were investigated using a high pressure lab-scale flowloop (Grasso 2015). In this part of the work, hydrate deposition mechanisms were evaluated by varying parameters such as liquid loading, water cut, subcooling, and liquid/gas phase velocity. The results from these laboratory-scale investigations show that both liquid and gas phase velocities have a high impact on the amount of hydrate formed in this system. The results from the investigations presented in this paper provide new insights into hydrate formation and deposition mechanisms. It is anticipated that such investigations can lead to new possibilities for more advanced hydrate management strategies for the flow assurance community.

Transportation of solids in form of slurries has become one of the most important unit operations in industries across several disciplines. In fact, the need is more pronounced in industries that are very important for human survival such as food processing, pharmaceuticals and energy (coal, oil and gas). A lot of work has been done in the past 30 years in understanding the factors affecting the deposition velocity of solids in slurries. Experimental observation and theoretical predictions pointed to mixture velocity and solid/fluid properties especially rheology of the resulting slurry to be the most important factors that dramatically affect particle motion and patterning. This paper presents a critical deposition velocity model and a ''stability flow map'' for complex rheology slurries. The critical deposition model utilizes a more robust generalized two-parameter rheology model to account for any given slurry rheology. The ''stability flow map'' demarcates the different flow patterns that may be observed at different mixture velocities and rheologies. On this map, the homogeneous slurries are predicted at low rheology and high mixture velocity, whereas heterogeneous slurries (with a concentration gradient) predicted at high rheology (yield stress effects). Sensitivity analysis was conducted on critical Reynolds number, particle density, carrier fluid density, generalized flow behavior index and pipe diameter. It was observed that increase in shear thinning behavior, particle density, pipe diameter and particle diameter led to a decrease in the laminar region and an increased unstable region. The model showed good performance when tested on glass and stainless steel beads test data available in open literature. Preliminary simulation with this map may help engineers select flowline size and carrier fluid rheology for a given type of solid particle.

Slurry transport has become a subject of interest in several industries, including oil and gas. The importance of slurry/solid transport in the oil and gas industry is evident in areas of cuttings transport, sand transport and, lately, hydrates. Hydrate formation, if not properly monitored and controlled, may lead to pipeline blockage. To avoid pipeline blockage and other hydrate formation risks, chemical additives are added to the system. Additives such as anti-agglomerants help improve hydrate transportability by dispersing the formed hydrates into slurries and preventing them from sticking to the pipe wall. This enables transportation of highly concentrated slurries. However, the high hydrate volume fractions (HVF) slurries may exhibit complex rheology. There is therefore a great need to correlate flow properties such as friction factor and viscosity to HVF. Hydrate slurry transport is important whether hydrates are deliberately generated for energy storage purposes or hydrates formed because of the prevailing flow conditions. However, when determining the viscosity of a fluid containing solid particles, the conventional viscometer types such as concentric cylinders and cone and plate are often not suitable. This is because either the narrow gap would not accommodate the particle size or their inability to maintain the particles suspended leading to bed formation. In this work, a high-pressure mixer-type viscometer was used to generate and characterize hydrate slurries. This work aims to generate a significant amount of hydrate slurry characterization data that may be used as basis for better rheometer designs, hydrate slurry flow properties modeling or integration of hydrate transportability into general multiphase modeling. Results showed that intermediate watercuts posed the greatest pipeline plugging risk for all the oils tested. The amount of transportable hydrates increased with oil viscosity. Generally, hydrate slurries generated exhibited shear thinning behavior that increased with increasing hydrate volume fraction. However, the overall rheology of these slurries is a complex function of the oil used, watercut, gas added to the system and hydrate solid fraction. Lowering shear rates for high HVF systems resulted in separation. Results in this work further suggest that hydrate transportation may be possible with minimum risk if anti-agglomerants are used and high enough shear is applied. On the other hand, if no anti-agglomerant is used, severe aggregation may result in flow line plugging.