No abstract

Yi-Tao Long opened a general discussion of the paper by Paul W. Bohn: The electrochemical nanoconnement makes a major impact on controlling the mass transport. Could you please comment on the multi-phase effects on the mass transport under nanoconnement. What's the next breakthrough application we could expected in controlling the mass transport in nanoconnement.

<p>Waste PLA can be upcycled to metal organic frameworks of potential high value in a one-pot synthesis scheme, where PLA depolymerisation occurs <i>in-situ</i>. Three lactate based frameworks were succesfully synthesised and characterised from PLA as a feed source, including homochiral framework ZnBLD. The chiral separation ability of ZnBLD was maintained.<br></p><p><br></p><p>Additional data including the CIF file, the CheckCIF document, and the raw XRD spectra, are available from the Zenodo repository linked below.<br></p>

Solvent induced enantioselectivity reversal is a rarely reported phenomenon in porous homochiral materials. Similar behaviour has been studied in chiral HPLC, where minor mobile phase modifications can induce elution order reversal. We report the first instance of solvent-induced enantioselectivity reversal for homochiral MOF ZnBLD, highlighting the complex enantioselectivity behaviour

<p>Waste PLA can be upcycled to metal organic frameworks of potential high value in a one-pot synthesis scheme, where PLA depolymerisation occurs <i>in-situ</i>. Three lactate based frameworks were succesfully synthesised and characterised from PLA as a feed source, including homochiral framework ZnBLD. The chiral separation ability of ZnBLD was maintained.<br></p><p><br></p><p>Additional data including the CIF file, the CheckCIF document, and the raw XRD spectra, are available from the Zenodo repository linked below.<br></p>