Nearly, 9 of 10 glaucoma patients were unable to instill eye drops correctly. This may be an important cause of unintentional noncompliance in glaucoma medical therapy.
Here,
we report the synthesis of vanadium diselenide (VSe
2
) three-dimensional
nanoparticles (NPs) and two-dimensional (2D)
nanosheets (NSs) utilizing nanosecond pulsed laser ablation technique
followed by liquid-phase exfoliation. Furthermore, a systematic study
has been conducted on the effect of NP and NS morphologies of VSe
2
in their catalytic activities toward oxygen reduction reaction
(ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction
(HER) under alkaline, neutral, and acidic conditions. Research on
VSe
2
clearly demonstrates that these morphologies do not
have a significant difference for ORR and OER; however, a drastic
effect of morphology was observed for HER. The ORR activity of both
NSs and NPs involves ∼2.85 numbers of electrons with the Tafel
slope of 120 mV/dec in alkaline and neutral pH. In alkaline solution,
NPs are proved to be an efficient catalyst for OER with an onset potential
1.5 V; however, for HER, NSs have a better onset potential of −0.25
V. Moreover, the obtained NPs have also better catalytic activity
with a 400 mV anodic shift in the onset potential compared to NSs.
These results provide a reference point for the future application
of VSe
2
in energy storage and conversion devices and mass
production of other 2D materials.
Qualitative chemical tests confirmed the presence of phytosterols, glycosides, tannins, and amino acids in the various leaf extracts of Moringa oleifera Lam., whereas its seed extracts showed the presence of phytosterols, glycosides, phenolic compounds, carbohydrates and amino acids. The ethanolic and ethyl acetate extracts of seeds showed significant antipyretic activity in rats, whereas ethyl acetate extract of dried leaves showed significant wound healing activity (10% extracts in the form of ointment) on excision, incision and dead space (granuloma) wound models in rats.
Portable and flexible energy devices demand lightweight and highly efficient catalytic materials for use in energy devices. An efficient water splitting electrocatalyst is considered an ideal future energy source. Well‐aligned high‐surface‐area electrospun polymers of intrinsic microporosity (PIM‐1)‐based nitrogen‐doped carbon nanofibers were prepared as a free‐standing flexible electrode. A non‐noble‐metal catalyst NiOOH/Ni(OH)2 was precisely deposited over flexible free‐standing carbon nanofibers by using atomic layer deposition (ALD). The morphology, high surface area, nitrogen doping, and Ni states synergistically showed a low onset potential (ηHER=−40 and ηOER=290 mV vs. reversible hydrogen electrode), small overpotential at η10 [oxygen evolution reaction (OER)=390.5 mV and hydrogen evolution reaction (HER)=−147 mV], excellent kinetics (Tafel slopes for OER=50 mV dec−1 and HER=41 mV dec−1), and high stability (>16 h) towards water splitting in an alkaline medium (0.1 m KOH). The performance was comparable with that of state‐of‐the‐art noble‐metal catalysts (e.g., Ir/C, Ru/C for OER, and Pt/C for HER). Post‐catalytic characterization with X‐ray photoelectron spectroscopy (XPS) and Raman spectroscopy further proved the durability of the electrode. This study provides insight into the design of 1D‐aligned N‐doped PIM‐1 electrospun carbon nanofibers as a flexible and free‐standing NiOOH/Ni(OH)2 decorated electrode as a highly stable nanocatalyst for water splitting in an alkaline medium.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.