The photoluminescent properties of Na, Bi co-doped CaWO4:Eu3+ phosphor under vacuum ultraviolet (VUV) region excited was investigated. A red emission of CaWO4:Eu3+ can be observed under 147 nm excitation. It was also found that the photoluminescence intensity of Na doped CaWO4:Eu3+ would be enhanced than the un-doped phosphors due to Na+ ions would act as a charge compensator and it can restrict the generation of defects in CaWO4:Eu3+. Additionally, the photoluminescence enhancement of Na+, Bi3+ co-doped CaWO4:Eu3+ should due to the energy transfer between WO42-, Bi3+ and Eu3+, and Bi3+ ions would act as a medium for the energy transfer, via WO42-Bi3+Eu3+. These are expected to be applying in plasma display panels.
In recent years, as a novel photocatalyst with the excellent ability to absorb visible light, BiVO4 has drawn increasing attention. In this paper, the photocatalytic mechanism and the electronic band structure of BiVO4 were introduced in detail. On the basis of main modifications of BiVO4, progress in BiVO4 photocatalyst for degradation was further reviewed. The aim of this work is to provide guideline for the intensive studies of BiVO4 in future.
A series of composites of the high photoactivity of {001} facets exposed BiOCl and grapheme sheets (GS) were synthesized via a one-step hydrothermal reaction. The obtained BiOCl/GS photocatalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, transmission electron microscopy (TEM), Ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy. The as-prepared BiOCl/GS photocatalyst showed enhanced photocatalytic activity for the degradation of methyl orange (MO) under UV and visible light (λ > 400 nm). The enhanced photocatalytic activity could be attributed to oxygen vacancies of the {001} facets of BiOCl/GS and the high migration efficiency of photo-induced electrons, which could suppress the charge recombination effectively.
In this paper, the synthesis methods of silver nanowires including template, self-assembled, hydrothermal synthesis and polyol methods are reviewed. In addition, the application and development of the silver nanowires are introduced.
ZnS nanocrystals were prepared via chemical precipitation method and characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), ultraviolet-visible (UV-vis) and photoluminescence (PL) spectra. The results indicated that the ZnS nanocrystals have cubic zinc blende structure and diameter is 3.68 nm as demonstrated by XRD. The morphology of nanocrystals is spherical measured by TEM which shows the similar particle size. The photoluminescence spectrum peaking at about 424 nm was due mostly to the trap-state emission, and a satellite peak at 480nm ascribed to the dangling bond of S in the surface of ZnS nanocrystals. The emission intensity of ZnS was enhanced after ultraviolet irradiation, the enhancement of the Photoluminescence intensity was due to the elimination of the surface defects after ultraviolet irradiation, for the growth of the coated shell on ZnS nonacrystals, the Photoluminescence intensity was increased as ultraviolet irradiation time growth, finally tends to be stable for the surface state of nanocrystals steady.
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