Zipper examined: High‐quality boron nitride nanoribbons (BNNRs) can be produced directly during nanotube synthesis without post‐treatment. These BNNRs are typically several micrometers long and tens of nanometers wide. Near‐edge X‐ray absorption fine structure investigations indicated that the BNNRs are of high chemical purity and crystallinity.
Fluorescent nanodiamonds
(FNDs) containing nitrogen-vacancy (NV)
centers as built-in fluorophores exhibit a nearly constant emission
profile over 550–750 nm upon excitation by vacuum-ultraviolet
(VUV), extreme ultraviolet (EUV), and X-radiations from a synchrotron
source over the energy (wavelength) range of 6.2–1450 eV (0.86–200
nm). The photoluminescence (PL) quantum yield of FNDs increases steadily
with the increasing excitation energy, attaining a value as great
as 1700% at 700 eV (1.77 nm). Notably, the yield curve is continuous,
having no gap in the VUV to X-ray region. In addition, no significant
PL intensity decreases were observed for hours. Applying the FND sensor
to measure the absorption cross-sections of gaseous O2 over
110–200 nm and comparing the measurements with the sodium-salicylate
scintillator, we obtained results in agreement with each other within
5%. The superb photostability and broad applicability of FNDs offer
a promising solution for the long-standing problem of lacking a robust
and reliable detector for VUV, EUV, and X-radiations.
The nitrogen-vacancy (NV) centers in diamond are among the most thoroughly investigated defects in solid-state matter;h owever,o ur understanding of their properties upon far-UV excitation of the host matrix is limited. This knowledge is crucial for the identification of NV as the carrier of extended red emission (ERE) bands detected in aw ide range of astrophysical environments.H erein, we report as tudy on the photoluminescence spectra of NV-containing nanodiamonds excited with synchrotron radiation over the wavelength range of 125-350 nm. We observed, for the first time,anemission at 520-850 nm with aq uantum yield greater than 20 %. Our results share multiple similarities with the ERE phenomena, suggesting that nanodiamonds are ac ommon component of dust in space.
The nitrogen-vacancy (NV) centers in diamond are among the most thoroughly investigated defects in solid-state matter; however, our understanding of their properties upon far-UV excitation of the host matrix is limited. This knowledge is crucial for the identification of NV as the carrier of extended red emission (ERE) bands detected in a wide range of astrophysical environments. Herein, we report a study on the photoluminescence spectra of NV-containing nanodiamonds excited with synchrotron radiation over the wavelength range of 125-350 nm. We observed, for the first time, an emission at 520-850 nm with a quantum yield greater than 20 %. Our results share multiple similarities with the ERE phenomena, suggesting that nanodiamonds are a common component of dust in space.
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