Insulating oil plays a crucial role in internal insulation of oil-impregnated transformers. It has been demonstrated in a variety of experimental studies that mineral oil (MO) and vegetable oil (VO) can be blended in different ratios to improve insulation properties; however, the mechanisms underlying this phenomenon remain unclear. In this study, a molecular dynamics (MD) simulation approach was used to investigate diffusion of water molecules in VO/MO blends and dielectric constants of a mixture. The results show that the diffusion coefficient of water molecules is negatively correlated with the proportion of VO; thus, addition of VO helps to improve the insulation properties of a mixture. Due to introduction of strong polar functional groups, a decrease in the diffusion behavior of water molecules can be attributed to an increase in the interaction energy and formation of hydrogen bonds between water molecules and the mixed oil system. There is a direct correlation between the dielectric constant of a mixture and VO content; however, it is very sensitive to water content. The presence of strong polar water molecules or functional groups in a mixture leads to an increase in the dielectric constant, which results in a reduction in insulating properties. Accordingly, presence of polar groups plays an important role in determining the insulating properties of a mixture. To increase the insulation performance of a mixture, it is important to consider the diffusion-inhibiting and dielectric effects of the stronger polar groups in vegetable oil compared to those in mineral oil.

As the thermal variation may change the total electron emission yield (TEEY) of materials and may ultimately result in unexpected surface charging, it is necessary to study the TEEY at various temperatures. In this research, we first updated the TEEY measurement system with a newly designed sample stage for different temperatures (−50, 25, and 100 °C) and the primary electron from 25 eV to 10 keV. By using the 30 μs/20 nA primary electron beam and sample scanning method to mitigate surface charging, the TEEY could be accurately obtained for dielectrics. Then, we chose a kind of polyimide film (Kapton 100H) used on spacecraft and a gold film sample to compare the TEEY at various temperatures. The results show that high temperature leads to higher TEEY of Kapton films, whereas 25 and −50 °C also leads to the same. On the other hand, the TEEY of gold remains the same at different temperatures. In the view of surface hole density and charge transportation, the TEEY variation of Kapton films was analyzed by bulk conduction, charge mobility, and the electron–hole recombination property. It is considered that the dissipation rate of holes is sensitive to temperature, and furthermore, the TEEY of Kapton films is dependent on temperature.

The operating safety of spacecraft in space environments is closely related to the surface discharging phenomenon of dielectrics such as polyimide (PI) film in solar arrays; moreover, carrier traps in the dielectric can affect its insulation performance. Therefore, to improve the vacuum surface flashover characteristics of PI film by nano modification and reveal the effect of trap distribution on the flashover of PI composite film, first, the original PI and nano-ZnO/PI composite films with different additive amounts (0.5, 1, 2, and 3 wt.%) were prepared by in situ polymerization and their performance was evaluated by the physicochemical properties characterized by methods such as thermogravimetric analysis; second, the surface traps of the original and nanocomposite films were measured and calculated by surface potential decay method, and the carrier mobility was also obtained; finally, the vacuum direct current (DC) surface flashover characteristics and bulk resistivity of all the film samples were measured and analyzed. The experiment results showed that with the increase in the amount of nano-ZnO, both the shallow and deep trap density increased significantly, while the trap energy varied slightly, and the surface flashover voltage also increased obviously. Based on the multi-core model, the increases in the shallow and deep trap density after the introduction of nano-ZnO into the PI matrix was analyzed from the microscopic perspective of the interface. Based on the comparative analysis of the trap distribution and surface flashover voltage characteristics, a bilayer model of vacuum DC surface flashover development was proposed. In the bilayer model, deep traps and shallow traps play a dominant role in the vacuum–solid interface and the inner surface of the dielectric, respectively, and increasing the trap density could effectively inhibit secondary electron multiplication on the surface and accelerate charge dissipation inside the film. Consequently, nano-ZnO can purposefully control the trap distribution, and then improve the flashover characteristics of nano-ZnO/PI composite films, which provides a new approach for improving the spacecraft material safety.

Due to the injection of energetic particles, such as electrons in space environment, the internal charging–discharging characteristics of spacecraft dielectrics need to be evaluated for the safety of spacecraft, and the evaluation results from experiments and simulations should be comparatively validated. An in-site pulsed electroacoustic (PEA) measurement system under high-energy electron radiation was established for evaluating the charging characteristics of thick plate samples about 3 mm, while a joint simulation method based on Geant4 and COMSOL was also proposed. The deposited charge distributions were compared through experiment and joint simulation method under 0.7, 1.0 and 1.3 MeV for 30 min and 1.0 MeV for 10, 60 and 120 min, respectively. Meanwhile, the electrostatic discharging characteristics were also comparative evaluated by both methods under 0.3 MeV for 20 min under 5, 10 and 15 µA beam current, and the total discharging times and initial discharging time were compared and analyzed. Overall, a good consistency existed between experimental and simulation results of charging–discharging characteristics under electron radiation while the difference was also analyzed in the perspective of dielectric properties, such as charge leakage by conduction. Through the comparative study, both evaluation methods are validated, which offers effective reference for the safety evaluation of spacecraft dielectrics in future.