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Studies have revealed that wood ash cement concrete just like other pozzolanic cement concrete has lower early strength compared to plain cement concrete. Nanoparticles have been found to improve the early strength of concrete due to its small size and large surface area. This paper reports the findings on influence of nanosilica on the workability and compressive strength of wood ash cement concrete. Wood ash was obtained as a waste product from Ladoke Akintola University of Technology (LAUTECH) bread bakery, Ogbomoso. Biological synthesis of nanosilica using kola pod extract and silica precursor (1:5) was conducted at Nanotechnology research group laboratory at LAUTECH. The chemical composition, specific gravity and grading of wood ash, fine and coarse aggregate used were determined. Concrete with 10% wood ash replacement for cement was produced using 1:2:4 mix proportion and water to binder ratio of 0.5. Nanosilica was added at 0.5, 1.0, 1.5 and 2.0% levels. Concrete with no wood ash and nanosilica served as the control. Workability and compressive strength of the plain and composite concrete were determined. The results showed that concrete workability was enhanced with introduction of nanosilica. The compressive strength also increased with the addition of nanosilica. Maximum compressive strength of 27.53MPa was achieved at 90 days with 1.5% nanosilica addition. It was concluded that nanosilica enhanced workability and improved both early and later strength development in wood ash concrete with 1.5% as the optimum addition.