This study was performed to develop and characterize a bio-film composed of Aloe vera (Aloe barbadensis), green banana Saba (Musa acuminata x balbisiana), and curcumin for the detection of Fe2+ ions. Cross-linking interaction between banana starch-aloe vera gel and banana starch-curcumin enhanced l the sensing performance of the composite film towards divalent metal ions of Fe2+. The morphological structure of the Aloe vera-banana starch-curcumin composite revealed a smooth and compact surface without cracks and some heterogeneity when observed under Scanning Electron Microscopy (SEM). The thickness, density, color property, opacity, biodegradation, moisture content, water-solubility, water absorption, swelling degree, and water vapor permeability of bio-films were measured. The incorporation of aloe vera gel and curcumin particles onto the banana starch film has successfully improved the film properties. The formation of the curcumin-ferrum (II) complex has triggered the film to transform color from yellow to greenish-brown after interaction with Fe2+ ions that exhibit an accuracy of 101.11% within a swift reaction time. Good linearity (R2 = 0.9845) of response on colorimetric analysis was also obtained in Fe2+ ions concentration that ranges from 0 to 100 ppm, with a limit of detection and quantification found at 27.84 ppm and 92.81 ppm, respectively. In this context, the film was highly selective towards Fe2+ ions because no changes of color occur through naked eye observation when films interact with other metal ions, including Fe3+, Pb2+, Ni2+, Cd2+, and Cu2+. Thus, these findings encourage curcumin-based starch films as sensing materials to detect Fe2+ ions in the field of food and agriculture.

In recent years, there has been much interest in developing advanced and innovative approaches for sensing applications in various fields, including agriculture and environmental remediation. The development of novel sensors for detecting heavy metals using nanomaterials has emerged as a rapidly developing research area due to its high availability and sustainability. This review emphasized the naturally derived and engineered nanomaterials that have the potential to be applied as sensing reagents to interact with metal ions or as reducing and stabilizing agents to synthesize metallic nanoparticles for the detection of heavy metal ions. This review also focused on the recent advancement of nanotechnology-based detection methods using naturally derived and engineered materials, with a summary of their sensitivity and selectivity towards heavy metals. This review paper covers the pros and cons of sensing applications with recent research published from 2015 to 2022.