Composición del aceite de la semilla del pistacho (Pistacia vera): efectos de la situación geográfica y de la variedad. Este estudio tiene como objetivo caracterizar cuatro cultivos de pistacho (Pistacia vera) de Túnez, de las regiones de Mateur (Norte), Nabeul (Nordeste), Kairouan (Centro) y Sfax (Centro-Este) y dos variedades, Mateur and Ohadi, considerando la composición en ácidos grasos y de lípidos mayoritarios (lípidos polares, diglicéridos, triglicéridos y ácidos grasos libres) de semillas maduras. Los lípidos se separaron mediante cromatografía en capa fina, y los ésteres metílicos de los ácidos grasos (FAMEs) se analizaron por cromatografía de gases. El ácido oleico (C18:1 ⌬ 9) fue el mayoritario en todas las muestras; las de la región de Mateur (Norte) fueron significativamente distintas, presentando el contenido más bajo de C18:1 (54.2 % del total de ácidos grasos) y más alto de C18:2 (24.1 %). La cantidad total de ácidos grasos (TFA) en las semillas de la variedad Ohadi fue significativamente más bajo que el de la variedad Mateur de la región de Sfax. Los triglicéridos fueron el componente más importante en la semillas de pistacho de Nabeul (98.5% del total de glicerolípidos).
Changes in fatty acids were studied during maturation of cumin (Cuminum cyminum L.) seeds cultivated in the North-Eastern region of Tunisia (Menzel Temim). The fruits matured in 49 Days after flowering (DAF). The first results show a rapid oil accumulation started in newly formed fruits (8.2%) and continued until their full maturity (16.9%). During fruit maturation, fatty acid profiles varied significantly among the three stages of maturity. Fruits development resulted mainly in an increase of petroselinic acid and a decrease of palmitic acid (C16:0). At full maturity, the main fatty acids were petroselinic acid (55.9%), followed by palmitic (23.82%), linoleic (12.40%) and pamitoleic (2.12%) acids. Polyunsaturated and monounsaturated fatty acids increased significantly; however, saturated fatty acids decreased during ripening of cumin seed. Results of this study indicate that the variation in the fatty acid composition of cumin seeds during maturation may be useful in understanding the source of nutritionally and industrially important fatty acids in this fruit. Cumin seed is potentially an important source of petroselinic acid which has numerous industrial applications.
The essential oils of seeds of Salvia verbenaca, Salvia officinalis, and Salvia sclarea were obtained by hydrodistillation and analyzed by gas chromatography (GC) and GC-mass spectrometry. The oil yields (w/w) were 0.050, 0.047, and 0.045% in S. verbenaca, S. sclarea, and S. officinalis, respectively. Seventy-five compounds were identified. The essential oil composition of S. verbenaca seeds showed that over 57% of the detected compounds were oxygenated monoterpenes followed by sesquiterpenes (24.04%) and labdane type diterpenes (5.61%). The main essential oil constituents were camphor (38.94%), caryophyllene oxide (7.28%), and 13-epi-manool (5.61%), while those of essential oil of S. officinalis were -thujone (14.77%), camphor (13.08%), and 1,8-cineole (6.66%). In samples of S. sclarea, essential oil consists mainly of linalool (24.25%), -thujene (7.48%), linalyl acetate (6.90%), germacrene-D (5.88%), bicyclogermacrene (4.29%), and -copaene (4.08%). This variability leads to a large range of naturally occurring volatile compounds with valuable industrial and pharmaceutical outlets.
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