Green synthesis of nanoparticles using various plant materials opens a new scope for the phytochemist and discourages the use of toxic chemicals. In this article, we report an eco-friendly and low-cost method for the synthesis of silver nanoparticles (AgNPs) using Andean blackberry fruit extracts as both a reducing and capping agent. The green synthesized AgNPs were characterized by various analytical instruments like UV-visible, transmission electron microscopy (TEM), dynamic light scattering (DLS), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The formation of AgNPs was analyzed by UV-vis spectroscopy at = 435 nm. TEM analysis of AgNPs showed the formation of a crystalline, spherical shape and 12-50 nm size, whereas XRD peaks at 38.04°, 44.06°, 64.34° and 77.17° confirmed the crystalline nature of AgNPs. FTIR analysis was done to identify the functional groups responsible for the synthesis of the AgNPs. Furthermore, it was found that the AgNPs showed good antioxidant efficacy (>78%, 0.1 mM) against 1,1-diphenyl-2-picrylhydrazyl. The process of synthesis is environmentally compatible and the synthesized AgNPs could be a promising candidate for many biomedical applications.
Silver nanoparticles (AgNPs) are fabricated using Sacha inchi (SI) or (Plukenetia volubilis L.) leaf extract as non-toxic reducing agent with particle size ranging from 4 to 25 nm. Optical, structural and morphological properties of the synthesized nanoparticles have been characterized by using Visual, UV-Vis spectrophotometer, transmission electron microscopy (TEM) and dynamic light scattering (DLS) analysis. Selected area electron diffraction (SAED) confirmed the formation of metallic Ag. Infrared spectrum measurement was carried out to hypothesize the possible phytochemicals responsible for stabilization and capping of the AgNPs. It shows the significant antioxidant efficacy in comparison with SI leaf extracts against 1,1-diphenyl-2-picrylhydrazyl. From the results obtained it is suggested that green AgNPs could be used effectively in future engineering and medical concerns.
Biofabrication of copper oxide nanoparticles (CuO-NPs) of a desired size remains a significant challenge. In this report, CuO-NPs were fabricated by treating 10 mM copper nitrate with Andean blackberry fruit (ABF) and leaf (ABL); and evaluated its antioxidant activity. As-prepared NPs characterization were determined by UVvisible spectrophotometry, Dynamic light scattering (DLS), Transmission electron microscopy (TEM) with selected area electron diffraction (SAED) and X-Ray Diffraction (XRD) analysis. UV-visible spectroscopy showed an electronic excitonic transition at 250 to 255 nm clearly reveals the formation of ABF and ABL CuO-NPs. DLS analysis demonstrated mean diameter of ABF CuO-NPs (43.3 nm) smaller than ABL CuO-NPs (52.5 nm). TEM with SAED confirmed the CuO-NPs are spherical and partial crystalline nature. Furthermore, the antioxidant efficacy of ABF CuO-NPs showed (89.02%, 1mM) whereas ABL CuO-NPs (75.92 %, 1mM) against 1, 1-diphenyl-2-picrylhydrazyl. From the results obtained it is suggested that green CuONPs could be used effectively in future biomedical concerns.
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