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[1] We present new volatile, trace element, and radiogenic isotopic compositions for rejuvenated-stage lavas erupted on Niihau and its submarine northwest flank. Niihau rejuvenated-stage Kiekie Basalt lavas are mildly alkalic and are isotopically similar to, though shifted to higher 87 Pb than, rejuvenated-stage lavas erupted on other islands and marginal seafloor settings. Kiekie lavas display trace element heterogeneity greater than that of other rejuvenated-stage lavas, with enrichments in Ba, Sr, and light-rare earth elements resulting in high and highly variable Ba/Th and Sr/Ce. The high Ba/Th lavas are among the least silica-undersaturated of the rejuvenated-stage suite, implying that the greatest enrichments are associated with the largest extents of melting. Kiekie lavas also have high and variable H 2 O/Ce and Cl/La, up to 620 and 39, respectively. We model the trace element concentrations of most rejuvenated-stage lavas by small degrees ($1% to 9%) of melting of depleted peridotite recently metasomatized by a few percent of an enriched incipient melt (0.5% melting) of the Hawaiian plume. Kiekie lavas are best explained by 4% to 13% partial melting of a peridotite source metasomatized by up to 0.2% carbonatite, similar in composition to oceanic carbonatites from the Canary and Cape Verde Islands, with lower proportion of incipient melt than that for other rejuvenated-stage lavas. Primary H 2 O and Cl of the carbonatite component must be high, but variability in the volatile data may be caused by heterogeneity in the carbonatite composition and/or interaction with seawater. Our model is consistent with predictions based on carbonated eclogite and peridotite melting experiments in which (1) carbonated eclogite and peridotite within the Hawaiian plume are the first to melt during plume ascent; (2) carbonatite melt metasomatizes plume and surrounding depleted peridotite; (3) as the plume rises, silica-undersaturated silicate melts are also produced and contribute to the metasomatic signature. The metasomatic component is best preserved at the margins of the plume, where low extents of melting of the metasomatized depleted mantle surrounding the plume are sampled during flexural uplift. Formation of carbonatite melts may provide a mechanism to transfer plume He to the margins of the plume.

The assemblage of ca. 28-3 Ma volcanic rocks exposed in the Lake Tahoe-Reno region of the northern Sierra Nevada, United States, is interpreted to be part of the Ancestral Cascades volcanic arc. The volcanic rocks are commonly highly porphyritic, including abundant plagioclase with clinopyroxene, amphibole, and rare biotite, and range from basaltic andesite to dacite in composition. Less common are poorly phyric, olivine-and clinopyroxene-bearing basalts and basaltic andesites. Porphyritic lavas dominate composite volcanic centers, whereas the poorly phyric lavas form isolated cinder cone and lava fl ow complexes. Tahoe-Reno arc lavas are calc-alkaline, enriched in the large ion lithophile elements but depleted in Nb and Ta relative to the light rare earth elements, and have highly variable radiogenic isotopic compositions. Compared to the modern south Cascade arc, Tahoe-Reno region basalts are enriched in the light rare earth and large ion lithophile elements and have higher 87 Sr/ 86 Sr and lower 143 Nd/ 144 Nd that are consistent with an old, subduction-modifi ed lithospheric mantle source, such as that proposed for lavas of the Western Great Basin. Melting of the lithospheric mantle may be enhanced by fl uid fl ux from the subducting slab if the Juan de Fuca slab dip is shallow. Andesites and dacites evolved from basaltic magmas by a combination of fractional crystallization and assimilation of lower crustal melts. Available geochronological data indicate that the westward sweep of Cenozoic volcanism through Nevada was associated with steepening of the slab dip, but the dip angle was lower during Miocene-Pliocene arc volcanism than it is today beneath the modern south Cascades.

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