Purpose This paper aims to evaluate the corrosion behavior of Ti-6Al-4V parts produced with electron beam melting (EBM) machine and compare it with wrought Ti-6Al-4V alloy. Design/methodology/approach Potentiodynamic and potentiostatic tests were applied on EBM Ti-6Al-4V in 3.5 per cent mass NaCl solution to determine the pitting potential and critical pitting temperature (CPT). A relation between pitting potential and temperature was established for EBM Ti-6Al-4V alloy by conducting potentiodynamic testing under different temperatures. CPT was also measured for EBM Ti-6Al-4V alloy in 3.5 per cent mass NaCl solution at a standard potential of 800 mV vs saturated calomel electrode (SCE). The same tests were performed on wrought Ti-6Al-4V for comparison purposes. Moreover, CPT for EBM Ti-6Al-4V alloy was measured in 3.5 per cent mass NaCl solution of different pH of 2.0, 5.7 and 10.0 to examine the effect of aggressive conditions on the pitting corrosion of EBM alloy. Findings Potentiodynamic test resulted in a relatively high pitting potential of EBM alloy, which was close to the pitting potential of wrought alloy even at higher temperatures. In addition, EBM samples did not pit when potentiostatic test was performed at 800 mV vs SCE, even at high and low values of pH. Originality/value EBM Ti-6Al-4V alloy has been increasingly playing an important role in aerospace, automobile and industrial fields. The technique and conditions of manufacturing form voids and increase roughness of the exterior surface of EBM objects, which might increase the tendency to initiate pitting corrosion within its holes and surface folds. This article shows that, despite surface variations and porosity in EBM Ti-6Al-4V alloy, the material maintained its corrosion resistance. It was found that the corrosion behavior of EBM alloy was close to that of the conventionally made wrought Ti-6Al-4V alloy.

Purpose This paper aims to study the effect of processing parameters of an electron beam melting (EBM) machine on the surface roughness, critical pitting temperature and density of Ti-6Al-4V parts produced from the EBM machine. Design/methodology/approach In this study, statistically designed experiments were used to manufacture Ti-6Al-4V samples in the EBM machine under different process parameters of beam current, beam speed and offset focus. Surface roughness was measured for as-built samples using a 3D profilometer. Then, a potentiostatic test was conducted under 2.40 V vs saturated calomel electrode to determine the critical pitting temperature (CPT) in 3.5 per cent mass NaCl solution for the samples of different processing parameters. Next, density was measured for these samples. Finally, model equations were established to relate EBM’s process parameters to measured properties of surface roughness, CPT and density. Findings Results showed that offset focus had the main influence on surface roughness more than the beam current and the beam speed. Changing processing parameters did not affect corrosion behavior of EBM Ti-6Al-4V as CPT did not vary widely, although a slight effect on CPT values obtained from the beam current and the beam speed. Density was greatly affected by the offset focus more than the other parameters. It can be concluded that uniform and precise measurements of roughness and density are not achievable through this machine; only a range of these properties can be attained. Originality/value EBM machine produces 3D parts in a layer-based building process under high temperature and vacuum atmosphere. Due to the manufacturing technique and conditions, the resulting object has irregularities on the exterior surface and voids that are formed within the part, both of which affect samples’ properties like surface roughness, CPT and density. This study established model equations that can relate parts’ properties to processing parameters so that parts of specific properties are obtained to fit the application they are used for. For each property, ANOVA fits vs linear energy were also obtained.

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A zinc oxide-based sorbent was prepared by spraying drying a slurry containing 65% zinc oxide, 18% peptized alumina, and 17% perlite. The spray dried solids were dry sieved, wet sieved, dried at 1508C for 1 h, and subsequently calcined at 6358C for 1 h to produce the sorbent. The rate of sorption of hydrogen sulfide was measured as a function of time with a Cahn VersaTherm TM thermogravimetric analyzer. Sorption rate is reported as a function of hydrogen sulfide partial pressure, temperature, and external particle size. Sorption rate can be described by a hydrogen sulfide mass-transport model for agglomerated particles. This agglomerate kinetics model satisfactory explains rate phenomena observed in this system.

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