Sucker rods are a key element in certain oil-extraction processes as they link the motor group on the surface with the pumps located downhole. During the transport from the production site toward the extraction well, these components are prone to corrosion. A hydrophobic carbon nanotube (CNT) coating, deposited via electrophoretic deposition (EPD), is proposed as a protective layer, shielding the rods from harsh environmental conditions. Three different coating systems are considered and thoroughly characterized (depending on the additive that is used to deposit the CNT), namely, magnesium nitrate hexahydrate (Mg-Nit), triethylamine (TEA), and a duplex coating (DD). The latter presents an approach which combines the advantages of each additive, mechanical stability from Mg-Nit and strong hydrophobicity from TEA (near superhydrophobic). The former coatings are further processed to overcome their individual shortcomings, resulting in an increase in the coating's stability for TEA coating, as well as transforming the hydrophilic Mg-Nit surface into a hydrophobic surface.
Copper is extensively used in a wide
range of industrial
and daily-life
applications, varying from heat exchangers to electrical wiring. Although
it is protected from oxidation by its native oxide layer, when subjected
to harsh environmental conditionssuch as in coastal regionsthis
metal can rapidly degrade. Therefore, in this study, we analyze the
potential use of carbon nanoparticle coatings as protective barriers
due to their intrinsic hydrophobic wetting behavior. The nanocarbon
coatings were produced via electrophoretic deposition on Cu platelets
and characterized via scanning electron microscopy, confocal laser
scanning microscopy, and sessile drop test; the latter being the primary
focus since it provides insights into the wetting behavior of the
produced coatings. Among the measured coatings, graphite flakes, graphene
oxide, and carbon nanotube (CNT) coatings showed superhydrophobic
behavior. Based on their wetting behavior, and specifically for electrical
applications, CNT coatings showed the most promising results since
these coatings do not significantly impact the substrate’s
electrical conductivity. Although CNT agglomerates do not affect the
wetting behavior of the attained coatings, the coating’s thickness
plays an important role. Therefore, to completely coat the substrate,
the CNT coating should be sufficiently thickabove approximately
1 μm.
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