Lamellar, or layered, potassium niobium oxide perovskites are a class of underdeveloped semiconductors in organic photocatalysis that offer the inherent advantages of larger particle size and ease of recoverability as compared to traditional semiconductor materials.
Novel gold nanoparticle@niobium oxide perovskite composites promote the photoreduction of para-substituted nitroarenes, where electron-withdrawing groups accelerate the photocatalytic reaction.
The photo-induced cytotoxicity of prodigiosenes is reported. One prodigiosene represents a synthetic analogue of the natural product prodigiosin, and two are conjugated to molecules that target the estrogen receptor (ER). A comparison of incubation and irradiation frameworks for the three prodigiosenes is reported, with activity against ER- and ER+ lines explored. Furthermore, the ability of the three prodigiosenes to photosensitise the production of singlet oxygen is demonstrated, shedding mechanistic light onto possible photodynamic therapeutic effects of this class of tripyrroles.
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