The purpose of this research was to fabricate starch based magnetic nanobiocomposites using 2 different starch types (corn and wheat) and to examine the effects of some experimental parameters (such as starch concentration, NaOH concentration and aging time of nanoparticles) that play a role in the synthesis products. The characterization of the starch-based magnetic-nanobiocomposite materials were realized with several techniques. The usability of starch-based magnetic-nanobiocomposite materials, which can provide rapid separation with their magnetic properties and are not toxic, in removing Sr (II) ions from aqueous solutions has been investigated. The parameters affecting the biosorption were investigated using a full factorial experimental design. In the biosorption study, pH, temperature, initial Sr(II) concentration and contact time were determined as four independent variables. The regression coefficients were found using the least squares method and the response surface graphs were created according to the polynomial equation obtained from the full factorial experimental design. ANOVA (analysis of variance) analysis within the 95% confidence interval of the model applied for the full factorial experimental design was examined and the compatibility of the model with the experimental findings was examine. The composition and chemical state of the magnetic nanobiocomposites were investigated by XPS analysis after Sr(II) biosorption. For the purpose of determine the adsorption model, the relevant parameters were calculated using Langmuir, Freundlich and Dubinin-Radushkevich isotherms. Gibbs free energy change, enthalpy and entropy values, which are the values of adsorption thermodynamics, were calculated.
The purpose of this research was to fabricate starch based magnetic nanobiocomposites using 2 different starch types (corn and wheat) and to examine the effects of some experimental parameters (such as starch concentration, NaOH concentration and aging time of nanoparticles) that play a role in the synthesis products. The characterization of the starch-based magnetic-nanobiocomposite materials were realized with several techniques. The usability of starch-based magnetic-nanobiocomposite materials, which can provide rapid separation with their magnetic properties and are not toxic, in removing Sr (II) ions from aqueous solutions has been investigated. The parameters affecting the biosorption were investigated using a full factorial experimental design. In the biosorption study, pH, temperature, initial Sr(II) concentration and contact time were determined as four independent variables. The regression coe cients were found using the least squares method and the response surface graphs were created according to the polynomial equation obtained from the full factorial experimental design.ANOVA (analysis of variance) analysis within the 95% con dence interval of the model applied for the full factorial experimental design was examined and the compatibility of the model with the experimental ndings was examine. The composition and chemical state of the magnetic nanobiocomposites were investigated by XPS analysis after Sr(II) biosorption. For the purpose of determine the adsorption model, the relevant parameters were calculated using Langmuir, Freundlich and Dubinin-Radushkevich isotherms. Gibbs free energy change, enthalpy and entropy values, which are the values of adsorption thermodynamics, were calculated.Recently, magnetic sorbents, especially those of vegetable origin have become very popular to remove impurities in water because they have properties such as low cost, easy preparation, fast sorbing ability,
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