Many quantum systems admit an explicit analytic Fourier space expansion, besides the usual analytic Schrödinger configuration space representation. We argue that the use of weighted orthonormal polynomial expansions for the physical states (generated through the power moments) can define an L 2 convergent, non-orthonormal, basis expansion with sufficient pointwise convergent behaviors, enabling the direct coupling of the global (power moments) and local (Taylor series) expansions in configuration space. Our formulation is elaborated within the orthogonal polynomial projection quantization (OPPQ) configuration space representation previously developed The quantization approach pursued here defines an alternative strategy emphasizing the relevance of OPPQ to the reconstruction of the local structure of the physical states.

The orthogonal polynomial projection quantization (OPPQ) is an algebraic method for solving Schrödinger’s equation by representing the wave function as an expansion in terms of polynomials orthogonal with respect to a suitable reference function R(x), which decays asymptotically not faster than the bound state wave function. The expansion coefficients are obtained as linear combinations of power moments . In turn, the 's are generated by a linear recursion relation derived from Schrödinger’s equation from an initial set of low order moments. It can be readily argued that for square integrable wave functions representing physical states . Rapidly converging discrete energies are obtained by setting Ω coefficients to zero at arbitrarily high order. This paper introduces an extention of OPPQ in momentum space by using the representation , where Qn(k) are polynomials orthogonal with respect to a suitable reference function T(k). The advantage of this new representation is that it can help solving problems for which there is no coordinate space moment equation. This is because the power moments in momentum space are the Taylor expansion coefficients, which are recursively calculated via Schrödinger’s equation. We show the convergence of this new method for the sextic anharmonic oscillator and an algebraic treatment of Gross–Pitaevskii nonlinear equation.

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