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The surface tension of a Lennard-Jones liquid–vapor interface has been determined accurately in a molecular dynamics simulation. Our values tend to be smaller than those from previous simulations. It is shown that the usually truncated tail of the potential strongly increases the surface tension if taken into account.

Most present day seismic migration schemes determine only the zero‐offset reflection coefficient for each grid point (depth point) in the subsurface. In matrix notation, the zero‐offset reflection coefficient is found on the diagonal of a reflectivity matrix operator that transforms the illuminating source‐wave field into a reflected‐wave field. However, angle dependent reflectivity information is contained in the full reflectivity matrix. Our objective is to obtain angle‐dependent reflection coefficients from seismic data by means of prestack migration (multisource, multioffset). After downward extrapolation of source and reflected wave fields to one depth level, the rows of the reflectivity matrix (representing angle‐dependent reflectivity information for each grid point at that depth level) are recovered by deconvolving the reflected wave fields with the related source wave fields. This process is carried out in the space‐frequency domain. In order to preserve the angle‐dependent reflectivity in the imaging we must not only add all frequency contributions but we should extend the imaging principle by adding along lines of constant angle in the wavenumber‐frequency domain. This procedure is carried out for each grid point. The resulting amplitude information provides a rigorous approach to amplitude‐versus‐offset related methods. The new imaging technique has been tested on media with horizontal layers. However, with our shot‐record oriented algorithm it is possible to handle any subsurface geometry. The first tests show excellent results up to high angles, both in the acoustic and in the elastic case. With angle‐dependent reflectivity information it becomes feasible to derive detailed velocity and density information in a subsequent stratigraphic inversion step.

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The curvature dependence of the liquid–vapor surface tension is described in the limit of small curvatures by Tolman’s length. Measurements of it, either experimentally or in a simulation, have not yet given a clear idea of its magnitude, even its sign is being debated. Previous attempts to relate Tolman’s length to a pressure tensor have led to ill-defined expressions. From an analysis of the pressure difference over the interface of a liquid drop, a pressure tensor expression is obtained for Tolman’s length that does not suffer from the previously encountered inconsistencies. This pressure difference is studied in a simulation of liquid drops, leading to an estimate of Tolman’s length. It appears to be small and bounds are given on it.