Bimodal associations of basalt and rhyolite of Upper Ordovician age which were erupted in a submarine environment occur within the Caledonian orogenic belt of South Britain at Parys Mountain (Anglesey), in Snowdonia (North Wales) and at Avoca (SE Ireland). The volcanic rocks have experienced hydrothermal alteration and low-grade metamorphism, and therefore immobile elements (e.g. Ti, Zr, Nb, Y) have been used to identify the original geochemical characteristics. The basalts have characters transitional between volcanic ‘arc’ and ‘within plate’ types consistent with eruption on an extensional part of an active continental margin. Two groups of rhyolites have been identified. A low-Zr group (Zr<500ppm), represented at all three locations, is interpreted as originally of high-K, subalkaline type. A high-Zr group (Zr>500ppm), represented at Snowdonia and Avoca, is interpreted as originally being peralkaline in composition; their high Zr/Nb ratios (>10) are typical of peralkaline rhyolites erupted above subduction zones. The bimodal nature of the associations and the peralkaline character of some rhyolites indicates magma production in a complex tectonic setting, transitional between an active continental margin/island arc and an extensional environment. Associated sulphide mineralization is volcanogenic and probably syn-sedimentary. High-level, rhyolitic magma chambers are thought to have driven convection of the hydrothermal fluids from which the sulphides precipitated.

The oldest igneous rocks on Maio are pillow lavas of Mid-Ocean Ridge pillow basalts character which have been tilted and uplifted about 4 km from the ocean floor to outcrop as a partial ring, dipping steeply away from a central plutonic complex made up of pyroxenites, essexites, syenites and carbonatites. The ocean floor volcanic rocks are overlain conformably by a stratigraphically continuous pelagic carbonate succession which demonstrates a shallowing depositional environment from the Upper Jurassic to Upper Cretaceous times, when tuffaceous beds indicate renewed volcanism. The tuffs are associated with rudites demonstrating the emergence of the island and amongst the clasts are plutonics indicating Upper Cretaceous magmatism and the unroofing of the volcano to a substantial depth. Deformation under compressive stress resulted in the folding and local repetition by thrusting of this sedimentary cover, which, together with the plutonic core, had been intensively injected by major sills. The Mesozoic succession has been planed off and overlain with marked unconformity by a largely Neogene sequence of volcanic and terrestrial sedimentary rocks. There is a hiatus throughout the Palaeogene, and constructional activity appears to recommence with ankaramitic hyaloclastite and lava deltas and subaerial ankaramitic flows. These are overlain by fluvial sediments and tuffs. Stratigraphically above these is an extensive plateau of silica-undersaturated lavas, olivine-melilitites and nephelinites, which rest on a planed and locally lateritized surface. At topographically higher levels in the eastern part of the island there are thick ankaramitic lavas and pyroclasts which evidently flowed eastward through valleys cut down into the Mesozoic strata, and appear to be of Pliocene age. The subsequent history of the island appears to be non-volcanic.

The Cadamosto Seamount is an unusual volcanic centre from Cape Verde, characterised by dominantly evolved volcanics, in contrast to the typically mafic volcanic centres at Cape Verde that exhibit only minor volumes of evolved volcanics. The magmatic evolution of Cadamosto Seamount is investigated to quantify the role of magma-crust interaction and thus provide a perspective on evolved end-member volcanism of Cape Verde. The preservation of mantle source signatures by Nd-Pb isotopes despite extensive magmatic differentiation provides new insights into the spatial distribution of mantle heterogeneity in the Cape Verde archipelago. Magmatic differentiation from nephelinite to phonolite involves fractional crystallisation of clinopyroxene, titanite, apatite, biotite and feldspathoids, with extensive feldspathoid accumulation being recorded in some evolved samples. Clinopyroxene crystallisation pressures of 0.38-0.17 GPa for the nephelinites constrain this extensive fractional crystallisation to the oceanic lithosphere, where no crustal assimilants or rafts of subcontinental lithospheric mantle are available. In turn, magma-crust interaction has influenced the Sr, O and S isotopes of the groundmass and late crystallising feldspathoids, which formed at shallow crustal depths reflecting the availability of oceanic sediments and anhydrite precipitated in the ocean crust. The Nd-Pb isotopes have not been affected by these processes of magmacrust interaction and hence preserve the mantle source signature. The Cadamosto Seamount samples have high 206 Pb/ 204 Pb ([19.5), high eNd (?6 to ?7) and negative D8/ 4Pb, showing affinity with the northern Cape Verde islands as opposed to the adjacent southern islands. Hence, the Cadamosto Seamount in the west is located spatially beyond the EM1-like component found further east. This heterogeneity is not encountered in the oceanic lithosphere beneath the Cadamosto Seamount despite greater extents of fractional crystallisation at oceanic lithospheric depths than the islands of Fogo and Santiago. Our data provide new evidence for the complex geometry of the chemically zoned Cape Verde mantle source.

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