Ultrathin two-dimensional
WSe2 has attracted huge attention
due to its potential applications in future wearable electronics.
Here, we demonstrate the flexible and high-performance photodetector
using high-yield sonochemical exfoliation technique. An efficient
and low cost fabrication strategy using Whatman filter paper is adopted
for the first time for fabrication of a photodetector based on WSe2 nanodots (NDs). The WSe2 NDs have hexagonal lattice
structure with P63/mmc and have indirect band gap of 1.63 eV. The exfoliation and number
of layers in WSe2 NDs is confirmed by Raman, absorption,
and photoluminescence spectroscopy. Subsequently, the photodetector
based on WSe2 NDs is fabricated. The device shows excellent
photoresponse with response time of 0.68 s and photoresponsivity of
17.78 mAW–1 and detectivity of 5.86 × 1010 Jones for 5 V. The device is analyzed for bias of 0 to 100
V and responsivity is enhanced up to 796.18 mA W–1 at 100 V bias. Furthermore, the paper-based detector exhibited great
flexibility and air stability. The performance of the photodetector
was also recorded in the spectral range 390 to 880 nm. Over all, the
performance paper-based device advocates a novel pathway for flexible
and intelligent electronics.
We
report a low-cost and green synthesis approach to produce high-performance
optoelectronics based on WS2-decorated pencil trace on
ordinary cellulose paper. It is noteworthy that the photodetector
was prepared via simply nontoxic solution-processed
WS2 nanosheets, pencil-drawn graphene conducting films,
and biodegradable papers. Portable and flexible electronics based
on WS2/graphene show excellent photoresponse in a broad
spectral region from visible to near IR because of plasmonic improvement
and efficient photoabsorption. Liquid-phase-exfoliated atomically
thin WS2 nanosheets were decorated on a conducting film
of pencil trace using the large area electrophoretic deposition technique.
The photodetector based on the WS2/graphene heterostructure
shows excellent temporal photoresponse with a responsivity of 0.439
A/W, a detectivity of 1.41 × 1010 Jones, and an external
quantum efficiency of 81.39%. The high-performance photodetector shows
piezoresistive modulation in electric transport. The device response
was investigated up to 500 bending cycles. Finally, the present finding
advocates the great development over previously reported nonbiodegradable
and small-area optoelectronic devices.
Recent research and development is focused in an intensive manner to increase the efficiency of solar energy conversion into electrical energy via photovoltaics and photo-electrochemical reactions.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.