We describe the design and fabrication trials of x-ray absorption gratings of 200 nm period and up to 100:1 depth-to-period ratios for full-field hard x-ray imaging applications. Hard x-ray phase-contrast imaging relies on gratings of ultra-small periods and sufficient depth to achieve high sensitivity. Current grating designs utilize lithographic processes to produce periodic vertical structures, where grating periods below 2.0 μm are difficult due to the extreme aspect ratios of the structures. In our design, multiple bilayers of x-ray transparent and opaque materials are deposited on a staircase substrate, and mostly on the floor surfaces of the steps only. When illuminated by an x-ray beam horizontally, the multilayer stack on each step functions as a micro-grating whose grating period is the thickness of a bilayer. The array of micro-gratings over the length of the staircase works as a single grating over a large area when continuity conditions are met. Since the layers can be nanometers thick and many microns wide, this design allows sub-micron grating periods and sufficient grating depth to modulate hard x-rays. We present the details of the fabrication process and diffraction profiles and contact radiography images showing successful intensity modulation of a 25 keV x-ray beam.

In this paper, we will demonstrate that excited dye molecules can be used to launch the plasmonic Bloch waves (PBWs) propagating at multi-metal-dielectric interfaces. The properties of the PBWs, such as wavevectors, propagating bands, the interface and grating period effect, were characterized by a leakage radiation microscope. Theoretical simulations were also carried out to reveal the properties of the PBWs and were consistent with the experimental results. What is more, experimental results reveal an interesting phenomenon: the PBWs launched by the excited dye molecules present different optical behaviors from those launched by far-field laser beams through attenuated total reflection. The mechanism of this difference was analyzed based on the energy conversion between the optical near-field and far-field. Our work provides a new way to launch the PBWs. Further, the coupling between the dye molecules and PBWs also demonstrates a new method to manipulate the fluorescence emission from random to controllable.