The pendant−core concept has been used previously to predict product
slates from catalytic
cracking. In this concept, alkyl side chains and analogous
moieties are defined as “pendants”,
which are attached to a cluster of aromatic and/or naphthenic rings
which is referred to as the
“core”. This work extends the pendant−core concept via a
model which correlates feed composition
(19 main component types determined by mass spectroscopy) to nine
product subclasses (both
gasoline and non-gasoline) by adding product distribution functions.
These product distribution
functions depend upon the feed component class (saturates, aromatics,
and sulfur compounds)
and upon the core−pendant ratio. For example, the production of
light gas and coke increases
with the core−pendant ratio since the probability of coke formation
increases with core size and
the average pendant chain length decreases as the proportion of carbon
in pendants decreases.
Using these component distribution functions, and the mass
spectroscopic analysis of feeds, one
can calculate anticipated yields of nine product subclasses: light
gas, C3/C4 gas, light cycle oils,
heavy cycle oils, coke, and gasoline range: paraffins, olefins,
aromatics, and naphthenes. The
product distribution functions were developed from data on four
feedstocks. For the four
feedstocks used in the correlation, plus a fifth feedstock, the
predicted product quantities are
within 2 wt % of the experimental values. The present form of the
model does not address effects
of polar (acidic or basic) compounds in feeds on product
slate.
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