Abstract.A technique is proposed for measuring the linear birefringence and linear diattenuation of an optical sample using a polarimeter. In the proposed approach, the principal axis angle (Į), phase retardance (ȕ), diattenuation axis angle (ș d ), and diattenuation (D) are derived using an analytical model based on the Mueller matrix formulation and the Stokes parameters. The dynamic measurement ranges of the four parameters are shown to be Į = 0~180°, ȕ = 0~180°, ș d = 0~180°, and D = 0~1, respectively. Thus, full-range measurements are possible for all parameters other than ȕ. In this study, the proposed methodology does not require the principal birefringence axes and diattenuation axes to be aligned. In addition, the linear birefringence and linear diattenuation properties are decoupled within the analytical model, and thus the birefringence properties of the sample can be solved directly without any prior knowledge of the diattenuation parameters.