A novel dilatometer has been used to measure the evolution of specific volume at different cooling rates and at elevated pressures under quiescent conditions and under shear for a series of commercial iPP homopolymers and polypropylene-ethylene random copolymers. Significant influences of cooling rates, pressures, and shear flow on the transition temperature T tr related to molecular weight and polydispersity and of course the temperature at which shearing was applied could be found for the iPP homopolymers. In the copolymers, the composition defined by the ethylene content determined the position of the transition temperature T tr .
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.