Density F and viscosity η were measured for binary mixtures of cotton seed + babassu and soybean + babassu biodiesel over the composition range at several temperatures of (293.15, 313.15, 333.15, 353.15, and 373.15) K and atmospheric pressure. The viscosity deviation (∆η) was determined and fitted by a Redlich-Kister type function in terms of mass fraction (w). The Joback's method combined with Lee-Kesler and Rackett equations were used to calculate the densities of the binary mixtures of cotton seed + babassu and soybean + babassu biodiesel. The experimental and estimated density values gave almost identical values with a relative differences of less than 0.21 %. The Ceriani's group contribution method was used to predict the viscosity, with a maximum relative deviation of 31 %.
The hydrometallurgical extraction of metals from spent lithium-ion batteries (LIBs) was investigated. LIBs were first dismantled and a fraction rich in the active material was obtained by physical separation, containing 95% of the initial electrode, 2% of the initial steel and 22% of plastic materials. Several reducers were tested to improve metals dissolution in the leaching step using sulphuric acid. Sodium metabisulphite led to the best results and was studied in more detail. The best concentration of NaSO was 0.1 M. The metals dissolution increased with acid concentration, however, concentrations higher than 1.25 M are unnecessary. Best results were reached using a stirring speed of 400 min. The metals leaching efficiency from the active material (Li, Mn, Ni, Co) increased with the temperature and was above 80% for temperatures higher than 60 °C. The dissolution of metals also rose with the increase in the liquid/solid ratio (L/S), however, extractions above 85% can be reached at L/S as lower as 4.5 L/kg, which is favourable for further purification and recovery operations. About 90% of metals extraction can be achieved after only 0.5 h of leaching. Sodium metabisulphite can be an alternative reducer to increase the leaching of Li, Mn, Co, and Ni from spent LIBs.
The three local hemostatic protocols were similarly effective in controlling postoperative bleeding in patients undergoing anticoagulant therapy with warfarin. The majority of teeth could be extracted with minimal problems in patients with cardiovascular diseases receiving treatment with anticoagulant therapy.
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