The molecular structures of 5-methyl-1,3-dithia-5-aziniumpresent when the distances between hydridic and protic hydrogen atoms are shorter than 265 pm and angles for Bcyclohexane iodide, 5-chloroborane-5-methyl-1,3-dithia-5-azacyclohexane, 3,5-bis(borane)-3,5-dimethyl-1-thia-3,5-di-N-C bonds are smaller than 107.6(3)°. These interactions explain the conformation of the borane adducts in the solid azacyclohexane, and 1-borane-1,3,5-trimethyl-1,3,5-triazacyclohexane were determined by X-ray diffraction studies.state. Interactions between hydridic and protic hydrogen atoms are ed, [1c] but is important for comparison with the data of 3

Primary arylamides were obtained when several aryl methyl ketones were treated with iodine in aqueous ammonia at room temperature in goods yields.Arilamidas primárias foram obtidas em bons rendimentos quando diversas arilmetilcetonas foram tratadas com iodo em amônia aquosa a temperatura ambiente.

The molecular structures of 5‐methyl‐1,3‐dithia‐5‐aziniumcyclohexane iodide, 5‐chloroborane‐5‐methyl‐1,3‐dithia‐5‐azacyclohexane, 3,5‐bis(borane)‐3,5‐dimethyl‐1‐thia‐3,5‐diazacyclohexane, and 1‐borane‐1,3,5‐trimethyl‐1,3,5‐triazacyclohexane were determined by X‐ray diffraction studies. Interactions between hydridic and protic hydrogen atoms are present when the distances between hydridic and protic hydrogen atoms are shorter than 265 pm and angles for B–N–C bonds are smaller than 107.6(3)°. These interactions explain the conformation of the borane adducts in the solid state.

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