In this paper, one uses the Tsallis entropy in the impact parameter space to study pp andpp inelastic overlap function and the energy density filling up mechanism responsible by the so-called black disk limit as the energy increases. The Tsallis entropy is non-additive and non-extensive and these features are of fundamental importance since the internal constituents of pp andpp are strongly correlated and also the existence of the multifractal character of the total cross-section. The entropy approach presented here takes into account a phase transition occurring inside the hadrons as the energy increases. This phase transition in the impact parameter space is quite similar to the Berezinskii-Kosterlitz-Thouless phase transition, possessing also a topological feature due to the multifractal dimension of the total cross-sections in pp andpp scattering.

We report on a new iron (iii)-cyamelurate-based coordination polymer. The new material based on a heptazine derivative was prepared in aqueous medium and characterized by a variety of techniques including TGA, FTIR, XRD, HRTEM, and STEM. Due to the high structural stability of the complex in aqueous media, its heterogeneous Fenton-like catalytic activity was evaluated using a model molecule. The results obtained showed a high catalytic activity in both in basic and acid media. The pseudo-first-order rate constants normalized by iron(III) concentrations was approximately 1000 times higher than the result obtained for traditional heterogeneous catalysts based on iron(III) oxyhydroxides. The best observed catalytic activities were attributed to the increase in the binding sites of Fe3+ ions, in parallel with the increased exposure of the catalytic sites, leading to a higher atomic efficiency of the reaction.