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The fluidized bed reactor is suitable for the combustion of biomass solid fuels because of its advantages in terms of pollution control. At the same time it is a useful laboratory tool to determine kinetic and diffusive combustion data in operating conditions similar to those found in industrial systems. Because of the heterogeneous nature of biomass, available information on its combustion is still limited. During the combustion of ligneous biomass, the burning of the solid carbonaceous residues formed after the initial steps of drying and volatiles release is the time-consuming step. In the present work, kinetic and diffusive data from the fluidized bed combustion of chars produced from four Portuguese wood speciesQuercus ilex (holm oak), Eucalyptus globulus (eucalyptus), Pinus pinaster (maritime pine), and Quercus suber (cork oak)were obtained in the 750–900 °C temperature range. Subsequently, activation energies and pre-exponential factors were calculated from the Arrhenius plot of the kinetic data. The obtained activation energies from 38 to 121 kJ/mol are coherent with results obtained for other wood chars and demonstrate that the fluidized bed technology is a fruitful and reliable methodology to achieve a collection of results of real and industrial interest. The main goal of the present work is to widen the information on the kinetic and diffusive data of wood chars in order to better understand the mechanisms of ligneous biomass combustion, and the data now published increases the range of available kinetic data on wood char combustion.

The combustion of biomass follows a sequence of several distinct phases which begin with drying, the subsequent pyrolysis with the release of volatile components that burn in gaseous phase and finally the combustion of carbonaceous resiue, the time consuming step. For small solid fuel boilers, as it is the case of pellet boilers for domestic heating, biomass particles are continuously burned in fixed bed boilers or heaters. In these appliances the furnace is a metallic basket into which fuel particles are thrown and burn. The combustion air is introduced through orifices drilled in this metallic basket although some lateral air entrances are also found. The gaseous flow is a piston flow, the particles fall under gravity on the upper bed surface and as they burn they slowly move downwards until their size is small enough to fall down through the air entrance orifices or are dragged by the upcoming combustion gas flow. So the gaseous current has an up flow movement while the solid particles move downwards. It is assumed that the bed is at uniform temperature and all the average properties of the gaseous flow are constant with the exception of the oxygen concentration that diminishes as the gas flow rises through the bed. The mathematical development of a simple model that allows the calculation of the steady state burning time of a biomass particle in fixed bed, the amount of energy released, the fixed bed size and its particle inventory, is hereby presented. The pedagogical interest of this model is pertinent because it presents, in a synthetic way, the relative importance of the combustion kinetic, the mass transfer mechanism and the reactor fluid dynamics, upon the lifetime of a biochar particle during its combustion process.

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