This paper presents an innovative approach, which enables control of the mechanical properties of metallic components by external stimuli to improve the mechanical behavior of aluminum structures in aeronautical applications. The approach is based on the exploitation of the shape memory effect of novel Shape Memory Alloy (SMA) coatings deposited on metallic structural components, for the purpose of relaxing the stress of underlying structures by simple heating at field-feasible temperatures, therefore enhancing their structural integrity and increasing their stiffness and rigidity while allowing them to withstand expected loading conditions safely. Numerical analysis provided an insight in the expected response of the SMA coating and of the SMA-coated element, while the dependence of alloy composition and heat treatment on the experienced shape memory effect were investigated experimentally. A two-phase process is proposed for deposition of the SMA coating in an order that induces beneficial stress relaxation to the underlying structure through the shape memory effect.

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Hydrodynamic cavitation (HC) has been extensively studied for the Advanced Oxidation of organic compounds in wastewaters since it physically produces an oxidative environment at ambient conditions. This process is simple and economical since it can be realized through a properly designed restriction in a pipeline, even in retrofit solutions. Several experimental works individuated similar values of the optimal operating conditions, especially with regard to the inlet pressure. Up to now, the available modeling works rely on a single-bubble dynamics (SBD) approach and do not consider the actual process configuration and pollutant transport in proximity to the oxidizing environment. This work describes different experimental results (from this research group and others) and applies a novel mathematical model based on a transport-phenomena approach, able to directly simulate the effect of HC on the pollutant degradation. The novel proposed model is able to reproduce well a large number of experimental data obtained in different conditions, with different apparatus and different molecules, and allows to interconnect both SBD, fluid-dynamics, and physio-chemical variables in order to deeply study the interaction between the transport of pollutants and the reactive environment. This paper includes collection and discussion of several experimental results with the related main process parameters, description of the novel model and validation against the cited experimental results (to explain the effect of the operating pressure), sensitivity analysis, and the performance limit of the HC with the proposed modeling approach.

Adsorptive wells arrays are an innovative outline of Permeable Reactive Barrier (PRBs) made of a definite number of passive deep wells opportunely distributed in the aquifer, known as PAB-D (Discontinuous Permeable Adsorptive Barrier). They are generally located downstream the contaminated groundwater flow and perpendicularly to the groundwater flow direction. Being PAB-D wells filled with adsorbing media, whose hydraulic permeability is higher than the surrounding media, the array will create a targeted capture zone, which will force the contaminated water to pass through the whole PAB-D, allowing for both the interception of the contaminant plume and its treatment. In this work, an optimized configuration of PAB-D is presented, for the in situ-remediation of an aquifer simultaneously contaminated by benzene and toluene. The design optimization of the PAB-D was performed by using COMSOL Multiphysics ® , in which numerical simulations reproduced the transport and the adsorptive phenomena occurring inside the aquifer and the barrier itself. The proposed technique was applied to the remediation of an aquifer located in an urban area in the north of Naples (Italy), in proximity of numerous landfills, where the contamination was spread over an area of 0.10 km 2. Simulation results confirm the effectiveness of the PAB-D, being both pollutant plumes intercepted and their concentrations reduced below their correspondent Italian regulatory threshold values. The best array configuration of PAB-D resulted made of 741 wells, each

is work aims at contributing to the development of a revolutionary technology based on shape memory alloy (SMA) coatings deposited on-site to large-scale metallic structural elements, which operate in extreme environmental conditions, such as steel bridges and buildings. e proposed technology will contribute to improve the integrity of metallic civil structures, to alter and control their mechanical properties by external stimuli, to contribute to the stiffness and rigidity of an elastic metallic structure, to safely withstand the expected loading conditions, and to provide corrosion protection. To prove the feasibility of the concept, investigations were carried out by depositing commercial NiTinol Ni50.8Ti (at.%) powder, onto stainless steel substrates by using high-velocity oxygen-fuel thermal spray technology. While the NiTinol has been known since decades, this intermetallic alloy, as well as no other alloy, was ever used as the SMA-coating material. Due to the influence of dynamics of spraying and the impact energy of the powder particles on the properties of thermally sprayed coatings, the effects of the main spray parameters, namely, spray distance, fuel-to-oxygen feed rate ratio, and coating thickness, on the quality and properties of the coating, in terms of hardness, adhesion, roughness, and microstructure, were investigated.