Thin lubrication flows accompanying drainage from curved surfaces surround us (e.g., the drainage of the tear film on our eyes). These draining aqueous layers are normally covered with surface-active molecules that render the free surface viscoelastic. The non-Newtonian character of these surfaces fundamentally alters the dynamics of drainage. We show that increased film stability during drainage can occur as a consequence of enhanced surface rheology. Increasing the surfactant layer viscosity decreases the rate of drainage; however, this retarding influence is most pronounced when the insoluble surfactant layer has significant elasticity. We also present a simple theoretical model that offers qualitative support to our experimental findings.

An interfacial phenomenon can be observed in the kitchen in a cup of black tea. When tea is left to cool after steeping, a thin film at the air–water interface can form. In certain conditions, this film is observable by naked eye and, when disturbed, cracks visibly like sea ice. The mechanical properties of this interfacial film are assessed using bicone interfacial rheometry. Water hardness, acidity, the presence of sugar or milk, tea concentration, and brewing temperature all affect the formation of this film. Interfaces formed in hard water (200 mg CaCO3/L) exhibit increased elastic modulus vs those in moderately hard water (100 mg CaCO3/L), soft water (50 mg CaCO3/L), and Milli-Q water. All films formed in chemically hardened water exhibit yielding point behavior in the interfacial oscillatory shear. Film physical thickness shows no correlation with measured physical strength. Conditions forming the strongest film, chemically hardened water, may be industrially useful in packaged tea beverages for preferable shelf stability and for emulsion stabilization of milk tea products. Conditions forming weakened films, addition of citric acid, may be useful for dried tea mixes. In lab conditions, the film visibility is obscured due to purity of tea ingredients and careful washing. However, the film physically forms and can still be measured through interfacial rheometry.

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