One of the great stories of geoscience is how Gondwana broke up and the other southern continents drifted northward from Antarctica, which led to major changes in global climate. The recent drilling of Ocean Drilling Project (ODP) Leg 189 addressed in detail what happened as Australia drifted away from Antarctica and the Tasmanian Gateway opened. The drifting contributed to the change in global climate, from relatively warm early Cenozoic “greenhouse” conditions to late Cenozoic “icehouse” conditions. It isolated Antarctica from warm gyral surface currents from the north and provided the critical deepwater conduits that eventually led to ocean conveyor circulation between the Atlantic and Pacific Oceans.

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A complex sedimentary sample from the Monterey Formation (CA, USA) has been submitted to GC-MS analysis followed by mass spectral deconvolution using Automated Mass Spectral Deconvolution and Identification System (AMDIS). Adjusting the parameters of the software allowed for the extraction of the spectrum of an unusual steroidal hydrocarbon coeluting with the major compound of the chromatogram. Following a careful interpretation of the "extracted" mass spectrum, the structure of the unknown has been postulated to be the 4,14-dimethylcholestane (DMC). Possible origins of this rare steroid are briefly discussed. Thus, application of AMDIS appears to be particularly suitable for the GC-MS analysis of natural complex mixtures characterized by a high number of analytes present in low amounts.

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