Corrosion in water-distribution systems is a costly problem and controlling corrosion is a primary focus of efforts to reduce lead (Pb) and copper (Cu) in tap water. High chloride concentrations can increase the tendency of water to cause corrosion in distribution systems. The effects of chloride are also expressed in several indices commonly used to describe the potential corrosivity of water, the chloride-sulfate mass ratio (CSMR) and the Larson Ratio (LR). Elevated CSMR has been linked to the galvanic corrosion of Pb whereas LR is indicative of the corrosivity of water to iron and steel. Despite the known importance of chloride, CSMR, and LR to the potential corrosivity of water, monitoring of seasonal and interannual changes in these parameters is not common among water purveyors. We analyzed long-term trends (1992-2012) and the current status (2010-2015) of chloride, CSMR, and LR in order to investigate the short and long-term temporal variability in potential corrosivity of US streams and rivers. Among all sites in the trend analyses, chloride, CSMR, and LR increased slightly, with median changes of 0.9mgL, 0.08, and 0.01, respectively. However, urban-dominated sites had much larger increases, 46.9mgL, 2.50, and 0.53, respectively. Median CSMR and LR in urban streams (4.01 and 1.34, respectively) greatly exceeded thresholds found to cause corrosion in water distribution systems (0.5 and 0.3, respectively). Urbanization was strongly correlated with elevated chloride, CSMR, and LR, especially in the most snow-affected areas in the study, which are most likely to use road salt. The probability of Pb action-level exceedances (ALEs) in drinking water facilities increased along with raw surface water CSMR, indicating a statistical connection between surface water chemistry and corrosion in drinking water facilities. Optimal corrosion control will require monitoring of critical constituents reflecting the potential corrosivity in surface waters.

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In‐stream sensors are increasingly deployed as part of ambient water quality‐monitoring networks. Temporally dense data from these networks can be used to better understand the transport of constituents through streams, lakes or reservoirs. Data from existing, continuously recording in‐stream flow and water quality monitoring stations were coupled with the two‐dimensional hydrodynamic CE‐QUAL‐W2 model to assess the potential of altered reservoir outflow management to reduce sediment trapping in John Redmond Reservoir, located in east‐central Kansas. Monitoring stations upstream and downstream from the reservoir were used to estimate 5.6 million metric tons of sediment transported to John Redmond Reservoir from 2007 through 2010, 88% of which was trapped within the reservoir. The two‐dimensional model was used to estimate the residence time of 55 equal‐volume releases from the reservoir; sediment trapping for these releases varied from 48% to 97%. Smaller trapping efficiencies were observed when the reservoir was maintained near the normal operating capacity (relative to higher flood pool levels) and when average residence times were relatively short. An idealized, alternative outflow management scenario was constructed, which minimized reservoir elevations and the length of time water was in the reservoir, while continuing to meet downstream flood control end points identified in the reservoir water control manual. The alternative scenario is projected to reduce sediment trapping in the reservoir by approximately 3%, preventing approximately 45 000 metric tons of sediment from being deposited within the reservoir annually. This article presents an approach to quantify the potential of reservoir management using existing in‐stream data; actual management decisions need to consider the effects on other reservoir benefits, such as downstream flood control and aquatic life. Copyright © 2012 John Wiley & Sons, Ltd.

Multiply By To obtain acre-foot (acre-ft) 1,233 cubic meter (m 3) acre-foot per square mile per year [(acre-ft/mi 2)/yr] Concentrations of chemical constituents in water are given either in milligrams per liter (mg/L) or micrograms per liter (µg/L). Densities of fecal-indicator bacteria are given in colonies per 100 milliliters of water (col/100 mL).