Faced with the AI (artificial intelligence) era, it is both theoretically and practically important to examine the challenges and opportunities that vocational college education in China faces, as well as to actively explore how vocational college education can overcome the challenges and achieve a realistic path. This paper proposes and implements a wireless network-based vocational college talent management system. The main personnel management system primarily completes business operations related to daily personnel file management, while the data mining subsystem mines talent data using the DT (decision tree) classification algorithm to aid talent selection. At the same time, a new topology optimization algorithm based on the principle of minimum rigidity graph is proposed for talent management system wireless network optimization. The maximum-minimum balance criterion and the user-by-user optimization mechanism are designed to obtain the optimal relay selection and subchannel allocation strategy, ensuring the system’s reliability and fairness. The optimized algorithm has a user security satisfaction of 0.93 in the range of 250 m, which is higher than other algorithms. It demonstrates that this algorithm’s communication link is short, and it has good network connectivity and structural stability.