N-Acylated perfluoroalkylated sulfoximines are synthesized easily from the corresponding free NH-sulfoximines on reaction with acid chlorides. This mild procedure is extended to diacid chlorides for the preparation of dimeric N-bridged sulfoximines and to reactions with chloroformates, carbamoyl chlorides, chlorothionoformates and thiocarbamoyl chlorides as electrophiles.

A Mild and Efficient Procedure for the N-Functionalization of S-Perfluoroalkylated Aryl Sulfoximines. -The title reaction is carried out with acid chlorides as reactants in the presence of base to give the corresponding functionalized amides. The method is extended to the synthesis of ureas, urethanes, thioureas, and C2-symmetrical bis-sulfoximes. -(MACE, Y.; CONSTANT-URBAN, C.; BOUVET, S.; PEGOT, B.; BOURNAUD, C.; TOFFANO, M.; VO-THANH, G.; DITER, P.; MAGNIER*, E.; Synthesis 45 (2013) 11, 1505-1512, http://dx.

The advance online publication (e-First) version of this article contained the incorrect mass spectral data for compounds 16 and 30.These errors have been corrected for both the current online version and the print publication.SYNTHESIS 2013, 45, 0001 Advanced online publication: 0 0 3 9 -7 8 8 1 1 4 3 7 -2 1 0 X