The management of oil-product pipelines represents a critical task in the daily operation of petroleum supply chains. Efficient computational tools are needed to perform this activity in a reliable and costeffective manner. This work presents a novel discrete event simulation system developed on Arena® for the detailed scheduling of a multiproduct pipeline consisting of a sequence of pipes that connect a single input station to several receiving terminals. The pipeline is modeled as a non-traditional multi-server queuing system involving a number of servers at every pipe-end that perform their tasks in a synchronized manner. Based on priority rules, the model decides which server should dispatch the entity waiting for service to the associated depot. Each priority rule can lead to a different delivery schedule, which is evaluated by using several criteria. Combined with optimization tools, the proposed simulation technique permits to easily manage real-world pipelines operations with low computational effort.

Phycocyanin, a blue protein extracted from Spirulina spp, shows promising characteristics that made it suitable for its use as natural dye in photovoltaic devices as the dye sensitized solar cells. In this work, a study of the aqueous solution-phase photochemistry, photophysics, spectroscopy, voltammetry and thermal stability of phycocyanin is presented. Suitable redox potentials (Eox = 1.2 V vs. Ag/AgCl) and a value of 1.96 V for E0,0 (i.e., the energy difference between the vibrationally relaxed levels of the first electronic excited state, S1, and the ground state, S0 of phycocyanin), allows the calculation of energetic profiles that in comparison with the conduction band of the anatase-TiO2 and I -/I3 electrolyte, could predict electron transfer with these components of the cell.The data reported herein should not only help to evaluate the potential use of phycocyanin as sensitizer for solar cells, but should also help in the development of novel solar cells where the photoinduced behavior of this protein can be controlled.

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