The stability of the novel Pu(IV) silicate, Cs2PuSi6O15, was predicted from a combination of crystal chemical reasoning and DFT calculations and confirmed by its synthesis via flux crystal growth. Formation...
A new series of rare earth thiophosphates, Rb4Ln2(P2S6)(PS4)2 (Ln = La, Ce, Pr, Nd, Sm, Gd), containing two unique thiophosphate motifs, [PVS4]3− and [PIV2S6]4−, were synthesized using the high temperature molten flux crystal growth method by RbBr flux.
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