Performance of new engineered material from epoxy resins with modified epoxidized natural rubber (ENR) and nanofillers were investigated. ENR from renewable natural crop resources is a type of green material with potential to partially substitute or replace and toughen petrochemical-based polymers. Nanocomposites (epoxy resin/ENR/fillers nanoparticles) were characterized with Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), atomic force microscope (AFM), and scanning electron microscopy (SEM). Comparison of characterized and mechanical properties of nanofiller reinforced with both nanocellulose and nanosilica were studied. The nanocomposites were characterized for their mechanical properties (e.g., impact strength, tensile strength) and thermal degradation behaviour by thermal gravimetric analysis (TGA). Mechanical property investigation results show that, the impact strength of nanocomposites, can be improved by blending in ENR 50 mixed with nanofiller, relative to the baseline nanocomposite mixers. The nanofiller loading in epoxy composite showed the highest improvement in mechanical properties at 0.75 phr (parts per hundred of resin). Effects of accelerated weathering aging were evaluated, and the observed changes were larger with nanosilica than with nanocellulose filler. Here, the accelerated aging increase in tensile properties was found to be 10% after 14 days in both nanofillers, while the other mechanical properties did not change significantly. These nanocomposites are expected to have high wear rates limiting their service life.
The objective of this study was to investigate nanocomposite materials with good outdoor resistance for wind turbine blade application. The nanocomposites based on epoxy resin with 5% of epoxidized natural rubber (ENR 50), 3% of nanofiller, and glass fibers, were subjected to experiments. The weathering resistance of nanocomposites was evaluated from the change in mechanical properties caused by accelerated aging, induced by UVB radiation in a weathering chamber. The accelerated aging improved tensile strength by about 35% at 168 h of exposure to UVB, via a curing effect. The nanocomposites were optimized for all the parts of wind turbine blades (Savonius and Darrieus types) that are generally designed for high strength, low weight, weathering resistance, and low rotational speed (2 m/s). A tree wind turbine with nanocomposite blades produced 5 kW power output when tested. Based on the findings in this work, the innovative nanocomposites have potential in manufacturing wind turbines to generate electricity.
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