Now a day’s researchers are focusing on natural fiber composites. In the present work composites were prepared with epoxy (Araldite LY-556) resin and ‘emu’ bird feathers as fiber. The composites were prepared by varying the weight percentage (P) of ‘emu’ fiber ranging from 1 to 5 and length (L) of feather fibers from 1 to 5 cm. The various mechanical properties like tensile strength, flexural strength; flexural modulus and impact strength were determined. An attempt is made to model the mechanical properties through response surface methodology (RSM). Analysis of Variance (ANOVA) is used to check the validity of the model. The results reveal that the developed models are suitable for prediction of mechanical properties of Epoxy ‘Emu’ Feather Fiber Composites.
Here, we report the observation of magneto-dielectric and magneto-structural coupling in (1 - x)BiFeO3-xPbTiO3 i.e.(1 - x)BF-xPT) solid solutions with compositions in the vicinity of morphotropic phase boundary, as manifested by a combination of temperature dependent magnetic, Raman and dielectric measurements. Whilst x-ray diffraction and Raman spectroscopy suggest absence of any structural phase transition between 90-300 K, temperature dependent magnetic studies reveal magnetic anomalies in the solid solutions. These results are complemented by identical observations in the dielectric measurements at similar temperatures indicating a coupling between magnetic and electric order parameters. Further, Raman studies on rhombohedral i.e. x = 0.20 samples reveal a coupling between the magnetic structure and the lattice, causing spin-phonon interactions that are possibly responsible for observed magneto-dielectric effects. Our results illustrate that the phase transitions in BiFeO3-PbTiO3 system are fewer than expected and are attributed to a spatial averaging in an inhomogeneous albeit single-phase material due to clustering of Fe- or Ti-ions on different length scales.
During induration at a high temperature, a considerable amount of slag/melt phase forms inside the iron ore pellets, comprising SiO 2 , Al 2 O 3 , CaO, MgO and FeO. After cooling, the slag phase solidifies and acts as an important bonding phase in the finished pellets and influences their room temperature as well as high temperature properties, especially reduction degradation. Fluxing agents play an important role in forming these bonding phases depending on the type and amount of flux. In the present study, the effect of different fluxing agents, namely, limestone, dolomite, magnesite and pyroxenite, on melt formation and microstructure during induration and on reduction degradation behaviour during reduction was examined. From the results, it was understood that to reduce the disintegration during reduction it is essential to increase the amount and distribution of bonding phases like silicates, which are more stable as compared to oxide phases like hematite. Acid pellets exhibited highest reduction degradation due to the presence of more hematite bonds and less silicate bonds. In limestone fluxed pellets, reduction degradation index dropped considerably with increasing CaO content due to the formation of more amount of bonding phase. Dolomite-pyroxenite pellets, on the other hand, showed lower reduction degradation index up to 0.4 basicity, and beyond that, higher degradation was observed due to the increased pore size, which resulted in poor strength of the reduced pellet matrix and hence more degradation. Low reduction degradation observed in pyroxenite and magnesite fluxed pellets could be due to the formation of magnesioferrite and silicate melt, which are more stable phases compared to hematite.
Pyroelectric current measurements on the orthorhombic GdMnO3 polycrystalline sample are done to explore the intrinsic and extrinsic contributions. The measurements reveal poling temperature dependent pyrocurrent peaks at 20, 50 and 108 K. The pyrocurrent at 20 K and at 108 K are attributed to ferroelectric transition induced by the incommensurate spiral magnetic ordering of Mn spins and the release of trapped charges from the localized states, respectively. A detailed analysis on the broad pyrocurrent signal at 50 K suggests that it could be attributed to the thermally stimulated depolarization current effect due to the relaxation of defect dipoles induced by negatively charged Mn3+ ions and excess holes localized at Mn4+ sites. Importantly, the effect of the electric field due to the defect dipoles on the ferroelectric state is highlighted. The temperature dependent dielectric measurements under the magnetic field brought out the correlation between pyroelectric and dielectric properties. The influence of poling temperature dependent extrinsic effects on pyrocurrent suggests the choice of poling temperature on the study of polarization and the resultant multiferroicity in a spin-driven ferroelectric rare earth manganite system.
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