Multiple potential parent species have been proposed to explain CN abundances in comet comae, but the parent has not been definitively identified for all comets. This study examines the spatial distribution of CN radicals in the coma of comet Encke and determines the likelihood that CN is a photodissociative daughter of HCN in the coma. Comet Encke is the shortest orbital period (3.3 years) comet known and also has a low dust-to-gas ratio based on optical observations. Observations of CN were obtained from 2003 October 22 to 24, using the 2.7 m telescope at McDonald Observatory. To determine the parent of CN, the classical vectorial model was modified by using a cone shape in order to reproduce Encke's highly aspherical and asymmetric coma. To test the robustness of the modified model, the spatial distribution of OH was also modeled. This also allowed us to obtain CN/OH ratios in the coma. Overall, we find the CN/OH ratio to be 0.009 ± 0.004. The results are consistent with HCN being the photodissociative parent of CN, but we cannot completely rule out other possible parents such as CH 3 CN and HC 3 N. We also found that the fan-like feature spans ∼90• , consistent with the results of Woodney et al..
Phase-change memory materials (PCMMs) are semiconductors that exhibit rapid order-disorder transition under electrical or optical pulse excitation. Currently thin-film-based PCMMs play a dominant role in fabrication of non-volatile memory devices. In contrast, phase-change nanowires (PCNWs) have the potential to overcome future challenges such as high data density and low power consumption. Among the various methods to synthesize PCNWs, the vapor-liquid-solid method has been reported previously. In this paper, we report synthesis of Sb-Te PCNWs using a templated electrochemical method. Nanoporous anodic aluminum oxide (AAO) was used as a template for the growth of nanowires. Sb-Te PCNWs with different compositions, diameters and aspect ratios were grown inside the AAO template by electrodeposition. Composition and structure of these nanowires were characterized by energy dispersive X-ray spectroscopy, X-ray diffraction, and scanning and transmission electron microscopy. It is found that electrodeposition through nanosized channels results in materials that are quite different from those electrodeposited on unrestricted surface. The mechanism of nanowire formation inside the channels of AAO template is discussed.
Amorphous Sb2Te3 thin films are synthesized using electrodeposition in different thicknesses to explore their solid electrolytic nature with respect to some noble metals. Au and Pt are used as the substrate materials and thermally diffused into the Sb2Te3 films under passivated and nonpassivated conditions. Rutherford backscattering spectrometry is used to study the Au and Pt diffusion into the films as a function of depth. It is found that Au diffuses into the Sb2Te3 thin films even at room temperature. In contrast, there is no observable diffusion of Pt at room temperature. At a higher temperature (i.e., 200 °C), both Au and Pt diffuse into the Sb2Te3 thin films and Au diffusion is more significant than Pt. The findings suggest that amorphous Sb2Te3 can be used as a good solid electrolyte to permit the diffusion of some noble metals such as Au and Pt.
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